TY - JOUR
T1 - Crystalline copper phosphates
T2 - Synthesis and thermal stability
AU - Bamberger, Carlos E.
AU - Specht, E. D.
AU - Anovitz, Lawrence M.
PY - 1997/12
Y1 - 1997/12
N2 - The syntheses of Cu(PO3)2, Cu2P2O7, Cu4P2O9, Cu5P2O10, Cu3(PO4)2, and Cu2PO4 were accomplished by several new solid-state routes. Attempts to synthesize CuPO3 were unsuccessful, and it is suspected that this compound, which is reported in the literature, may not exist. The thermal stabilities of Cu(PO3)2, Cu2P2O7 and Cu3(PO4)2 were examined, and their decomposition was concluded to be strongly dependent on slow kinetics.
AB - The syntheses of Cu(PO3)2, Cu2P2O7, Cu4P2O9, Cu5P2O10, Cu3(PO4)2, and Cu2PO4 were accomplished by several new solid-state routes. Attempts to synthesize CuPO3 were unsuccessful, and it is suspected that this compound, which is reported in the literature, may not exist. The thermal stabilities of Cu(PO3)2, Cu2P2O7 and Cu3(PO4)2 were examined, and their decomposition was concluded to be strongly dependent on slow kinetics.
UR - http://www.scopus.com/inward/record.url?scp=0031360816&partnerID=8YFLogxK
U2 - 10.1111/j.1151-2916.1997.tb03241.x
DO - 10.1111/j.1151-2916.1997.tb03241.x
M3 - Article
AN - SCOPUS:0031360816
SN - 0002-7820
VL - 80
SP - 3133
EP - 3138
JO - Journal of the American Ceramic Society
JF - Journal of the American Ceramic Society
IS - 12
ER -