Crystal structure of triphenyl(vinyl)phosphonium tetraphenylborate

Joseph L. Bradfield; Richard A. Braun; Frankie White; Jeffrey M. Hendrich; Richard E. Sykora; Arsalan Mirjafari

doi:10.1107/S1600536814021357

Crystal structure of triphenyl(vinyl)phosphonium tetraphenylborate

Joseph L. Bradfield
, Richard A. Braun
, Frankie White
, Jeffrey M. Hendrich
, Richard E. Sykora
, Arsalan Mirjafari

Research output: Contribution to journal › Article › peer-review

Abstract

The title ionic salt, C₂₁H₂₀P⁺ C₂₄H₂₀B^-, crystallized with two independent vinyltriphenylphosphonium cations and two independent tetraphenylborate anions per asymmetric unit. These four independent moieties contain nearly perfect tetrahedral symmetry about their respective central C atoms. In the crystal, there are no π-stacking or other intermolecular interactions present.

Original language	English
Pages (from-to)	o1143
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	70
Issue number	10
DOIs	https://doi.org/10.1107/S1600536814021357
State	Published - Oct 1 2014
Externally published	Yes

Keywords

crystal structure
ionic salt
tetraphenylborate
vinyltriphenylphosphonium

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10.1107/S1600536814021357

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title = "Crystal structure of triphenyl(vinyl)phosphonium tetraphenylborate",

abstract = "The title ionic salt, C21H20P+ C24H20B-, crystallized with two independent vinyltriphenylphosphonium cations and two independent tetraphenylborate anions per asymmetric unit. These four independent moieties contain nearly perfect tetrahedral symmetry about their respective central C atoms. In the crystal, there are no π-stacking or other intermolecular interactions present.",

keywords = "crystal structure, ionic salt, tetraphenylborate, vinyltriphenylphosphonium",

author = "Bradfield, \{Joseph L.\} and Braun, \{Richard A.\} and Frankie White and Hendrich, \{Jeffrey M.\} and Sykora, \{Richard E.\} and Arsalan Mirjafari",

year = "2014",

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doi = "10.1107/S1600536814021357",

language = "English",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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T1 - Crystal structure of triphenyl(vinyl)phosphonium tetraphenylborate

AU - Bradfield, Joseph L.

AU - Braun, Richard A.

AU - White, Frankie

AU - Hendrich, Jeffrey M.

AU - Sykora, Richard E.

AU - Mirjafari, Arsalan

PY - 2014/10/1

Y1 - 2014/10/1

N2 - The title ionic salt, C21H20P+ C24H20B-, crystallized with two independent vinyltriphenylphosphonium cations and two independent tetraphenylborate anions per asymmetric unit. These four independent moieties contain nearly perfect tetrahedral symmetry about their respective central C atoms. In the crystal, there are no π-stacking or other intermolecular interactions present.

AB - The title ionic salt, C21H20P+ C24H20B-, crystallized with two independent vinyltriphenylphosphonium cations and two independent tetraphenylborate anions per asymmetric unit. These four independent moieties contain nearly perfect tetrahedral symmetry about their respective central C atoms. In the crystal, there are no π-stacking or other intermolecular interactions present.

KW - crystal structure

KW - ionic salt

KW - tetraphenylborate

KW - vinyltriphenylphosphonium

UR - https://www.scopus.com/pages/publications/84907899855

U2 - 10.1107/S1600536814021357

DO - 10.1107/S1600536814021357

M3 - Article

AN - SCOPUS:84907899855

SN - 1600-5368

VL - 70

SP - o1143

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 10

ER -

Crystal structure of triphenyl(vinyl)phosphonium tetraphenylborate

Abstract

Keywords

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