TY - GEN
T1 - CO2 chemistry at Nankai group
T2 - Catalytic conversion of co 2 into value-added chemicals
AU - He, Liang Nian
AU - Yang, Zhen Zhen
AU - Liu, An Hua
AU - Gao, Jian
PY - 2010/12/3
Y1 - 2010/12/3
N2 - Carbon dioxide is very attractive as a typical renewable feedstock for manufacturing commodity chemicals, fuels and materials since it is an abundant, nontoxic, nonflammable and easily available carbon resource. In this context, development of catalytic methodologies for chemical transformation of CO 2 into useful compounds is of paramount importance from a standpoint of C1 chemistry and green chemistry. Great efforts have been directed towards constructing C-C, C-O and C-N bond on the basis of CO2 activation through molecular catalysis owing to its kinetic and thermodynamic stability. The aim of this chapter is to demonstrate the versatile use of CO2 in organic synthesis, with the main focus on utilization of CO2 as a building block for synthesis of industrial useful compounds such as cyclic carbonates, oxazolidinones, lactones, quinazolines, etc. The potential use of dense CO2 as an alternative solvent and otherwise specific roles in organic synthesis are also evaluated. The most results presented herein could be based on our recent research work on CO2 chemistry.
AB - Carbon dioxide is very attractive as a typical renewable feedstock for manufacturing commodity chemicals, fuels and materials since it is an abundant, nontoxic, nonflammable and easily available carbon resource. In this context, development of catalytic methodologies for chemical transformation of CO 2 into useful compounds is of paramount importance from a standpoint of C1 chemistry and green chemistry. Great efforts have been directed towards constructing C-C, C-O and C-N bond on the basis of CO2 activation through molecular catalysis owing to its kinetic and thermodynamic stability. The aim of this chapter is to demonstrate the versatile use of CO2 in organic synthesis, with the main focus on utilization of CO2 as a building block for synthesis of industrial useful compounds such as cyclic carbonates, oxazolidinones, lactones, quinazolines, etc. The potential use of dense CO2 as an alternative solvent and otherwise specific roles in organic synthesis are also evaluated. The most results presented herein could be based on our recent research work on CO2 chemistry.
UR - http://www.scopus.com/inward/record.url?scp=84905459430&partnerID=8YFLogxK
U2 - 10.1021/bk-2010-1056.ch006
DO - 10.1021/bk-2010-1056.ch006
M3 - Conference contribution
AN - SCOPUS:84905459430
SN - 9780841225961
T3 - ACS Symposium Series
SP - 77
EP - 101
BT - Advances in CO2 Conversion and Utilization
PB - American Chemical Society
ER -