Corrosion of 316H stainless steel in flowing FLiNaK salt

Stephen S. Raiman, J. Matthew Kurley, Dino Sulejmanovic, Adam Willoughby, Scott Nelson, Keyou Mao, Chad M. Parish, M. Scott Greenwood, Bruce A. Pint

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Abstract

Type 316H stainless steel samples were exposed to flowing FLiNaK salt for 1000 h in a monometallic thermal convection loop (TCL) with a maximum temperature of 650 °C and a minimum of 540 °C. Samples in the hottest part of the TCL lost mass, with a maximum mass loss of 1.4 mg/cm2, while samples in the coldest parts of the TCL gained mass, with a maximum mass gain of 1.0 mg/cm2. Analysis of the samples that gained mass showed an Fe-rich layer on the sample surfaces, indicating that Fe, not Cr, was the primary deposition product in the TCL. Cr loss was apparent to a depth of ∼5 µm in the hot leg. Post-exposure analysis of the salt showed major increases in the Cr, Fe, and Mn contents. The TCL was modeled using the TRANSFORM code. Modeled values matched the experimental temperature measurements showing that TRANSFORM is capable of accurately simulating the TCL conditions.

Original languageEnglish
Article number153551
JournalJournal of Nuclear Materials
Volume561
DOIs
StatePublished - Apr 1 2022

Funding

The authors acknowledge the assistance of Jim Keiser, Tracie Lowe, and Victoria Cox at ORNL. This work was funded by the U.S. Department of Energy, Office of Nuclear Energy, Molten Salt Reactor Campaign.

FundersFunder number
Molten Salt Reactor Campaign
U.S. Department of Energy
Office of Nuclear Energy
Oak Ridge National Laboratory

    Keywords

    • Corrosion
    • Fluoride Salt
    • MSR
    • Molten salt
    • Molten salt reactor
    • Stainless steel

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