Core/Shell Pd/FePt nanoparticles as an active and durable catalyst for the oxygen reduction reaction

Vismadeb Mazumder; Miaofang Chi; Karren L. More; Shouheng Sun

doi:10.1021/ja1024436

Core/Shell Pd/FePt nanoparticles as an active and durable catalyst for the oxygen reduction reaction

Vismadeb Mazumder, Miaofang Chi, Karren L. More, Shouheng Sun

Research output: Contribution to journal › Article › peer-review

359 Scopus citations

Abstract

We report a unique synthesis of core/shell Pd/FePt nanoparticles (NPs) and their catalysis of the oxygen reduction reaction (ORR). The uniform FePt shell is formed by controlled nucleation of Fe(CO)₅ in the presence of a Pt salt and Pd NPs at designated reaction temperatures. The Pd/FePt NPs show FePt shell-dependent catalytic properties, and those having a 1 nm FePt shell exhibit a drastic increase in durability and activity (15 times more active with a 140 mV gain in onset potential in comparison with those having a 3 nm coating). These Pd/FePt NPs are promising new catalysts for practical fuel cell applications.

Original language	English
Pages (from-to)	7848-7849
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	132
Issue number	23
DOIs	https://doi.org/10.1021/ja1024436
State	Published - Jun 16 2010

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title = "Core/Shell Pd/FePt nanoparticles as an active and durable catalyst for the oxygen reduction reaction",

abstract = "We report a unique synthesis of core/shell Pd/FePt nanoparticles (NPs) and their catalysis of the oxygen reduction reaction (ORR). The uniform FePt shell is formed by controlled nucleation of Fe(CO)5 in the presence of a Pt salt and Pd NPs at designated reaction temperatures. The Pd/FePt NPs show FePt shell-dependent catalytic properties, and those having a 1 nm FePt shell exhibit a drastic increase in durability and activity (15 times more active with a 140 mV gain in onset potential in comparison with those having a 3 nm coating). These Pd/FePt NPs are promising new catalysts for practical fuel cell applications.",

author = "Vismadeb Mazumder and Miaofang Chi and More, \{Karren L.\} and Shouheng Sun",

year = "2010",

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T1 - Core/Shell Pd/FePt nanoparticles as an active and durable catalyst for the oxygen reduction reaction

AU - Mazumder, Vismadeb

AU - Chi, Miaofang

AU - More, Karren L.

AU - Sun, Shouheng

PY - 2010/6/16

Y1 - 2010/6/16

N2 - We report a unique synthesis of core/shell Pd/FePt nanoparticles (NPs) and their catalysis of the oxygen reduction reaction (ORR). The uniform FePt shell is formed by controlled nucleation of Fe(CO)5 in the presence of a Pt salt and Pd NPs at designated reaction temperatures. The Pd/FePt NPs show FePt shell-dependent catalytic properties, and those having a 1 nm FePt shell exhibit a drastic increase in durability and activity (15 times more active with a 140 mV gain in onset potential in comparison with those having a 3 nm coating). These Pd/FePt NPs are promising new catalysts for practical fuel cell applications.

AB - We report a unique synthesis of core/shell Pd/FePt nanoparticles (NPs) and their catalysis of the oxygen reduction reaction (ORR). The uniform FePt shell is formed by controlled nucleation of Fe(CO)5 in the presence of a Pt salt and Pd NPs at designated reaction temperatures. The Pd/FePt NPs show FePt shell-dependent catalytic properties, and those having a 1 nm FePt shell exhibit a drastic increase in durability and activity (15 times more active with a 140 mV gain in onset potential in comparison with those having a 3 nm coating). These Pd/FePt NPs are promising new catalysts for practical fuel cell applications.

UR - https://www.scopus.com/pages/publications/77953318051

U2 - 10.1021/ja1024436

DO - 10.1021/ja1024436

M3 - Article

AN - SCOPUS:77953318051

SN - 0002-7863

VL - 132

SP - 7848

EP - 7849

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 23

ER -

Core/Shell Pd/FePt nanoparticles as an active and durable catalyst for the oxygen reduction reaction

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