Copper-based alloys for structural high-heat-flux applications: a review of development, properties, and performance of Cu-rich Cu–Cr–Nb alloys

Robert P. Minneci, Eric A. Lass, Jeffrey R. Bunn, Hahn Choo, Claudia J. Rawn

Research output: Contribution to journalReview articlepeer-review

65 Scopus citations

Abstract

This review examines the development and current state of Cu-rich Cu–Cr–Nb alloys commonly referred to as GRCop or Glenn Research copper alloys with emphasis on Cu–8Cr–4Nb (at%), or GRCop-84, and Cu–4Cr–2Nb, or GRCop-42. Recent additive manufacturing efforts have increased interest in GRCop alloys, and full-scale hardware has been fabricated using AM techniques and practical hot-fire tests have been conducted, but structure–property relationships are still under development. The development, processing, and current microstructure-property relationships of GRCop alloys are reviewed along with comparisons to similar high-heat-flux Cu alloys including NARloy-Z, GlidCop Al-15, AMZIRC, Cu–1Cr–0.1Zr, and Cu–0.9Cr. The review concludes with an assessment of future prospects for GRCop alloys and overview of advantages provided by additive manufacturing.

Original languageEnglish
Pages (from-to)394-425
Number of pages32
JournalInternational Materials Reviews
Volume66
Issue number6
DOIs
StatePublished - 2021

Funding

This work was supported by National Science Foundation: [Grant Number IIP1540000]; National Science Foundation: [Grant Number IIP1822186]; Oak Ridge National Laboratory: [Grant Number Graduate Opportunities (GO!)]. The authors would like to acknowledge the Manufacturing and Materials Joining Innovation Center (Ma2JIC), made possible through awards NSF IIP-1540000 (Phase I) and NSF IIP-1822186 (Phase II) from the National Science Foundation Industry University Cooperative Research Center program (IUCRC). RPM also acknowledges the financial support of the Center for Materials Processing at the University of Tennessee, Knoxville and Oak Ridge National Laboratory’s Graduate Opportunities (GO!) Program. Special thanks to David Ellis of NASA GRC and Paul Gradl of NASA MSFC for their discussions and comments on this review and historical information. The authors would like to acknowledge the Manufacturing and Materials Joining Innovation Center (MaJIC), made possible through awards NSF IIP-1540000 (Phase I) and NSF IIP-1822186 (Phase II) from the National Science Foundation Industry University Cooperative Research Center program (IUCRC). RPM also acknowledges the financial support of the Center for Materials Processing at the University of Tennessee, Knoxville and Oak Ridge National Laboratory’s Graduate Opportunities (GO!) Program. Special thanks to David Ellis of NASA GRC and Paul Gradl of NASA MSFC for their discussions and comments on this review and historical information. 2

FundersFunder number
MaJIC
Manufacturing and Materials Joining Innovation Center
NASA MSFC
National Science Foundation Industry University
National Science Foundation1822186, IIP-1822186, IIP-1540000
Oak Ridge National Laboratory
University of Tennessee

    Keywords

    • High-heat-flux
    • additive manufacturing
    • combustion chamber liner
    • creep
    • dispersion strengthening
    • low-cycle thermal fatigue
    • powder metallurgy
    • precipitation hardening
    • thermal conductivity

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