Abstract
A simple and versatile strategy, borrowing ideas from the chemistry of MOFs and COFs, is developed for the synthesis of coordination-supported organic polymers (COPs) via coordination between Al3+ and 5-amino-8-hydroxyquinoline together with organic imine- or imide-based polycondensation. The COPs with high surface areas (up to 1123 m2 g-1) and abundant mesopores (2.5 nm or 14 nm) possess good crystalline and porous structure after being soaked in boiling water.
| Original language | English |
|---|---|
| Pages (from-to) | 2018-2022 |
| Number of pages | 5 |
| Journal | Inorganic Chemistry Frontiers |
| Volume | 5 |
| Issue number | 8 |
| DOIs | |
| State | Published - Aug 2018 |
Funding
This paper was prepared in honor of Professor Ruren Xu for his forty-year contribution in zeolitic materials research. SD would like to thank Prof. Xu for his guidance and support over years. P. F. Z. and S. D. were supported by the U.S. Department of Energy, Office of Science, Basic Energy Sciences, Chemical Sciences, Geosciences, and Biosciences Division. The electron microscopy at ORNL (S. Z. Y.) was supported by the U.S. Department of Energy, Office of Science, Basic Energy Sciences, Materials Sciences and Engineering Division. P. F. Z. acknowledges Shanghai Pujiang Program (Grant No. 17PJ1403500), Young Thousand Talented Program and National Natural Science Foundation of China (Grant No. 21776174) for the partial support.
| Funders | Funder number |
|---|---|
| Shanghai Pujiang Program | 17PJ1403500 |
| U.S. Department of Energy | |
| Office of Science | |
| Basic Energy Sciences | |
| Oak Ridge National Laboratory | |
| Division of Materials Sciences and Engineering | |
| Chemical Sciences, Geosciences, and Biosciences Division | |
| National Natural Science Foundation of China | 21776174 |