Confinement effect on the adsorption from a binary liquid system near liquid/liquid phase separation

Gernot Rother; Dirk Woywod; Martin Schoen; Gerhard H. Findenegg

doi:10.1063/1.1755667

Confinement effect on the adsorption from a binary liquid system near liquid/liquid phase separation

Gernot Rother, Dirk Woywod, Martin Schoen, Gerhard H. Findenegg

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

The preferential adsorption of one component of a binary system into the inner surfaces of mesoporous silica glass was investigated at temperatures close to liquid/liquid phase separation. Three controlled pore glass materials of different mean pore sizes were used to analyze the confinement effect on adsorption. Strong preferential adsorption of water was found to take place in an experimental system that exhibited an upper miscibility gap. The area-related surface excess amount of water was also observed to decrease with decreasing pore size in the strong adsorption regime, while the shift in the volume-related mean composition of the pore liquid showed an opposite trend.

Original language	English
Pages (from-to)	11864-11873
Number of pages	10
Journal	Journal of Chemical Physics
Volume	120
Issue number	24
DOIs	https://doi.org/10.1063/1.1755667
State	Published - Jun 22 2004
Externally published	Yes

Access to Document

10.1063/1.1755667

Cite this

@article{27171d3a5e934910a88acfc5d0137db0,

title = "Confinement effect on the adsorption from a binary liquid system near liquid/liquid phase separation",

abstract = "The preferential adsorption of one component of a binary system into the inner surfaces of mesoporous silica glass was investigated at temperatures close to liquid/liquid phase separation. Three controlled pore glass materials of different mean pore sizes were used to analyze the confinement effect on adsorption. Strong preferential adsorption of water was found to take place in an experimental system that exhibited an upper miscibility gap. The area-related surface excess amount of water was also observed to decrease with decreasing pore size in the strong adsorption regime, while the shift in the volume-related mean composition of the pore liquid showed an opposite trend.",

author = "Gernot Rother and Dirk Woywod and Martin Schoen and Findenegg, \{Gerhard H.\}",

year = "2004",

month = jun,

day = "22",

doi = "10.1063/1.1755667",

language = "English",

volume = "120",

pages = "11864--11873",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "24",

}

TY - JOUR

T1 - Confinement effect on the adsorption from a binary liquid system near liquid/liquid phase separation

AU - Rother, Gernot

AU - Woywod, Dirk

AU - Schoen, Martin

AU - Findenegg, Gerhard H.

PY - 2004/6/22

Y1 - 2004/6/22

N2 - The preferential adsorption of one component of a binary system into the inner surfaces of mesoporous silica glass was investigated at temperatures close to liquid/liquid phase separation. Three controlled pore glass materials of different mean pore sizes were used to analyze the confinement effect on adsorption. Strong preferential adsorption of water was found to take place in an experimental system that exhibited an upper miscibility gap. The area-related surface excess amount of water was also observed to decrease with decreasing pore size in the strong adsorption regime, while the shift in the volume-related mean composition of the pore liquid showed an opposite trend.

AB - The preferential adsorption of one component of a binary system into the inner surfaces of mesoporous silica glass was investigated at temperatures close to liquid/liquid phase separation. Three controlled pore glass materials of different mean pore sizes were used to analyze the confinement effect on adsorption. Strong preferential adsorption of water was found to take place in an experimental system that exhibited an upper miscibility gap. The area-related surface excess amount of water was also observed to decrease with decreasing pore size in the strong adsorption regime, while the shift in the volume-related mean composition of the pore liquid showed an opposite trend.

UR - https://www.scopus.com/pages/publications/3142694936

U2 - 10.1063/1.1755667

DO - 10.1063/1.1755667

M3 - Article

AN - SCOPUS:3142694936

SN - 0021-9606

VL - 120

SP - 11864

EP - 11873

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 24

ER -

Confinement effect on the adsorption from a binary liquid system near liquid/liquid phase separation

Abstract

Access to Document

Other files and links

Fingerprint

Cite this