Computational Methodology to Simulate Pyrometallurgical Processes in a Secondary Lead Furnace

Vivek M. Rao, Vineet Kumar, Alexandra Anderson, Joseph Grogan, Prashant K. Jain

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

Pyrometallurgical recovery of nonferrous metals involves a combination of thermally intensive transformations during exothermic gas-phase reactions, endothermic decomposition of solid charge, and melting of simpler solids. In the recovery of secondary lead, simultaneous thermal effects in a reverberatory-style furnace cause a melt pool to accumulate at the bottom, with lighter solids (slag) floating above and gaseous products from decomposition of the charge diffusing through the gas–slag interface. Species from oxy-fuel combustion of natural gas, species profiles from smelting reactions, and the formation of a melt pool consisting primarily of lead are simulated via a time-averaged formulation. Predictions of outflow are compared with preset inflow profiles to ensure conservation of mass. Thermal profiles for solid, liquid, and gas phases are presented by species. A novel method is implemented to model the latent heat of fusion using a heterogeneous chemical reaction. The simulation is conducted in Simcenter STAR-CCM+ v. 16.02.009-R8.

Original languageEnglish
Title of host publicationREWAS 2022
Subtitle of host publicationDeveloping Tomorrow’s Technical Cycles
EditorsAdamantia Lazou, Katrin Daehn, Camille Fleuriault, Mertol Gökelma, Elsa Olivetti, Christina Meskers
PublisherSpringer Science and Business Media Deutschland GmbH
Pages503-513
Number of pages11
ISBN (Print)9783030925628
DOIs
StatePublished - 2022
Event7th Installment of the REWAS conference series held at the TMS Annual Meeting and Exhibition focuses on developing tomorrow’s technical cycles, 2022 - Anaheim, United States
Duration: Feb 27 2022Mar 3 2022

Publication series

NameMinerals, Metals and Materials Series
ISSN (Print)2367-1181
ISSN (Electronic)2367-1696

Conference

Conference7th Installment of the REWAS conference series held at the TMS Annual Meeting and Exhibition focuses on developing tomorrow’s technical cycles, 2022
Country/TerritoryUnited States
CityAnaheim
Period02/27/2203/3/22

Bibliographical note

Publisher Copyright:
© 2022, The Minerals, Metals & Materials Society.

Funding

This work was sponsored by the US Department of Energy, Office of Energy Efficiency and Renewable Energy (EERE), Advanced Manufacturing Office, High Performance Computing for Energy Innovation Program (HPC4EI), under contract DE-AC05-00OR22725 with UT-Battelle, LLC. The HPC4EI Program is managed by Lawrence Livermore National Laboratory for the US Department of Energy.

FundersFunder number
U.S. Department of Energy
Advanced Manufacturing OfficeDE-AC05-00OR22725, HPC4EI
Office of Energy Efficiency and Renewable Energy

    Keywords

    • CFD
    • DEM
    • Lead
    • Melting
    • Oxy-fuel combustion
    • Smelting

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