Abstract
Pyrometallurgical recovery of nonferrous metals involves a combination of thermally intensive transformations during exothermic gas-phase reactions, endothermic decomposition of solid charge, and melting of simpler solids. In the recovery of secondary lead, simultaneous thermal effects in a reverberatory-style furnace cause a melt pool to accumulate at the bottom, with lighter solids (slag) floating above and gaseous products from decomposition of the charge diffusing through the gas–slag interface. Species from oxy-fuel combustion of natural gas, species profiles from smelting reactions, and the formation of a melt pool consisting primarily of lead are simulated via a time-averaged formulation. Predictions of outflow are compared with preset inflow profiles to ensure conservation of mass. Thermal profiles for solid, liquid, and gas phases are presented by species. A novel method is implemented to model the latent heat of fusion using a heterogeneous chemical reaction. The simulation is conducted in Simcenter STAR-CCM+ v. 16.02.009-R8.
Original language | English |
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Title of host publication | REWAS 2022 |
Subtitle of host publication | Developing Tomorrow’s Technical Cycles |
Editors | Adamantia Lazou, Katrin Daehn, Camille Fleuriault, Mertol Gökelma, Elsa Olivetti, Christina Meskers |
Publisher | Springer Science and Business Media Deutschland GmbH |
Pages | 503-513 |
Number of pages | 11 |
ISBN (Print) | 9783030925628 |
DOIs | |
State | Published - 2022 |
Event | 7th Installment of the REWAS conference series held at the TMS Annual Meeting and Exhibition focuses on developing tomorrow’s technical cycles, 2022 - Anaheim, United States Duration: Feb 27 2022 → Mar 3 2022 |
Publication series
Name | Minerals, Metals and Materials Series |
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ISSN (Print) | 2367-1181 |
ISSN (Electronic) | 2367-1696 |
Conference
Conference | 7th Installment of the REWAS conference series held at the TMS Annual Meeting and Exhibition focuses on developing tomorrow’s technical cycles, 2022 |
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Country/Territory | United States |
City | Anaheim |
Period | 02/27/22 → 03/3/22 |
Bibliographical note
Publisher Copyright:© 2022, The Minerals, Metals & Materials Society.
Funding
This work was sponsored by the US Department of Energy, Office of Energy Efficiency and Renewable Energy (EERE), Advanced Manufacturing Office, High Performance Computing for Energy Innovation Program (HPC4EI), under contract DE-AC05-00OR22725 with UT-Battelle, LLC. The HPC4EI Program is managed by Lawrence Livermore National Laboratory for the US Department of Energy.
Funders | Funder number |
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U.S. Department of Energy | |
Advanced Manufacturing Office | DE-AC05-00OR22725, HPC4EI |
Office of Energy Efficiency and Renewable Energy |
Keywords
- CFD
- DEM
- Lead
- Melting
- Oxy-fuel combustion
- Smelting