Comment on 'Resonant inelastic x-ray scattering from U3O8and UN'

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Abstract

In a recent manuscript, Lawrence Brightet al(2023J. Phys.: Condens. Matter35175501) reported the resonant inelastic x-ray scattering spectra of U3O8, as well as UN. Their goal was to identify electronic multiplets associated with a 5f1configuration with ground state2F5/2. Complete active space self-consistent field with spin-orbit coupling (CASSCF-SOC) predicted that2F5/2transitions should be observable at 190 and 328 meV. However, these energies were not accessible in their experiment. They suggested that the recent inelastic neutron scattering results of Miskowiecet al(2021Phys. Rev.B103205101) could have been sensitive to these transitions. Here we show that transitions of this possible origin appear in that dataset near 198, 262, 362, and potentially 448 meV.

Original languageEnglish
JournalJournal of Physics Condensed Matter
Volume36
Issue number50
DOIs
StatePublished - Sep 23 2024

Keywords

  • magnetic ordering
  • neutron scattering
  • uranium oxide

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