Abstract
This report describes an ultrafast, large-area, and highly flexible method to construct complex two- and three-dimensional silicon nanostructures with deterministic non-close-packed symmetry. Pulsed excimer laser irradiation is used to induce a transient melt transformation of amorphous silicon filled in a colloidal self-assembly-directed inverse opal template, resulting in a nanostructured crystalline phase. The pattern transfer yields are high, and long-range order is maintained. This technique represents a potential route to obtain silicon nanostructures of various symmetries and associated unique properties for advanced applications such as energy storage and generation.
| Original language | English |
|---|---|
| Pages (from-to) | 7960-7966 |
| Number of pages | 7 |
| Journal | ACS Nano |
| Volume | 5 |
| Issue number | 10 |
| DOIs | |
| State | Published - Oct 25 2011 |
| Externally published | Yes |
Keywords
- colloidal crystals
- crystalline
- non-close-packed
- pulsed laser irradiation
- self-assembly
- silicon