Collision-induced dissociation of lanthanide oxide ions in quadrupole ion traps: Effects of bond strength and mass

Glen P. Jackson; Fred L. King; Douglas E. Goeringer; Douglas C. Duckworth

doi:10.1016/S1387-3806(02)00549-3

Collision-induced dissociation of lanthanide oxide ions in quadrupole ion traps: Effects of bond strength and mass

Glen P. Jackson
, Fred L. King
, Douglas E. Goeringer
, Douglas C. Duckworth

Applied Materials Analysis

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

Collision-induced dissociation (CID) rates are measured for a suite of lanthanide (plus yttrium) monoxide ions stored in a quadrupole ion trap. Yttrium, neodymium, and gadolinium oxides, having the same nominal dissociation energy (D₀ ≈ 735 kJ mol^-1) but different masses, provide an empirical correction of -1.2s^-1 amu^-1 for the measured CID rates. The CID rate correction enables the correlation of bond dissociation energy with CID rate, allowing quantitative determinations of bond dissociation energies for lanthanide metal monoxide ions. For bond dissociation energies in the range of 567-849 kJ mol^-1, mass corrected rates range from 50 to 120 s^-1. The calibration sensitivity is equivalent to 5 kJ mol^-1 s^-1, and the measurement precision is ∼25 kJ mol^-1. Bond energy determinations are found to agree with the average values reported for lanthanide oxide ions.

Original language	English
Pages (from-to)	85-93
Number of pages	9
Journal	International Journal of Mass Spectrometry
Volume	216
Issue number	1-2
DOIs	https://doi.org/10.1016/S1387-3806(02)00549-3
State	Published - Apr 15 2002

Funding

Research sponsored by the Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, U.S. Department of Energy, under contract DE-AC05-00OR22725 with Oak Ridge National Laboratory, managed and operated by UT-Battelle, LLC. Discussions with Scott A. McLuckey of Purdue University in the early stages of this work are gratefully acknowledged.

Keywords

Bond strength
Collision-induced dissociation
Lanthanide oxide ions

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10.1016/S1387-3806(02)00549-3

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title = "Collision-induced dissociation of lanthanide oxide ions in quadrupole ion traps: Effects of bond strength and mass",

abstract = "Collision-induced dissociation (CID) rates are measured for a suite of lanthanide (plus yttrium) monoxide ions stored in a quadrupole ion trap. Yttrium, neodymium, and gadolinium oxides, having the same nominal dissociation energy (D0 ≈ 735 kJ mol-1) but different masses, provide an empirical correction of -1.2s-1 amu-1 for the measured CID rates. The CID rate correction enables the correlation of bond dissociation energy with CID rate, allowing quantitative determinations of bond dissociation energies for lanthanide metal monoxide ions. For bond dissociation energies in the range of 567-849 kJ mol-1, mass corrected rates range from 50 to 120 s-1. The calibration sensitivity is equivalent to 5 kJ mol-1 s-1, and the measurement precision is ∼25 kJ mol-1. Bond energy determinations are found to agree with the average values reported for lanthanide oxide ions.",

keywords = "Bond strength, Collision-induced dissociation, Lanthanide oxide ions",

author = "Jackson, \{Glen P.\} and King, \{Fred L.\} and Goeringer, \{Douglas E.\} and Duckworth, \{Douglas C.\}",

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T1 - Collision-induced dissociation of lanthanide oxide ions in quadrupole ion traps

T2 - Effects of bond strength and mass

AU - Jackson, Glen P.

AU - King, Fred L.

AU - Goeringer, Douglas E.

AU - Duckworth, Douglas C.

PY - 2002/4/15

Y1 - 2002/4/15

N2 - Collision-induced dissociation (CID) rates are measured for a suite of lanthanide (plus yttrium) monoxide ions stored in a quadrupole ion trap. Yttrium, neodymium, and gadolinium oxides, having the same nominal dissociation energy (D0 ≈ 735 kJ mol-1) but different masses, provide an empirical correction of -1.2s-1 amu-1 for the measured CID rates. The CID rate correction enables the correlation of bond dissociation energy with CID rate, allowing quantitative determinations of bond dissociation energies for lanthanide metal monoxide ions. For bond dissociation energies in the range of 567-849 kJ mol-1, mass corrected rates range from 50 to 120 s-1. The calibration sensitivity is equivalent to 5 kJ mol-1 s-1, and the measurement precision is ∼25 kJ mol-1. Bond energy determinations are found to agree with the average values reported for lanthanide oxide ions.

AB - Collision-induced dissociation (CID) rates are measured for a suite of lanthanide (plus yttrium) monoxide ions stored in a quadrupole ion trap. Yttrium, neodymium, and gadolinium oxides, having the same nominal dissociation energy (D0 ≈ 735 kJ mol-1) but different masses, provide an empirical correction of -1.2s-1 amu-1 for the measured CID rates. The CID rate correction enables the correlation of bond dissociation energy with CID rate, allowing quantitative determinations of bond dissociation energies for lanthanide metal monoxide ions. For bond dissociation energies in the range of 567-849 kJ mol-1, mass corrected rates range from 50 to 120 s-1. The calibration sensitivity is equivalent to 5 kJ mol-1 s-1, and the measurement precision is ∼25 kJ mol-1. Bond energy determinations are found to agree with the average values reported for lanthanide oxide ions.

KW - Bond strength

KW - Collision-induced dissociation

KW - Lanthanide oxide ions

UR - https://www.scopus.com/pages/publications/0037090720

U2 - 10.1016/S1387-3806(02)00549-3

DO - 10.1016/S1387-3806(02)00549-3

M3 - Article

AN - SCOPUS:0037090720

SN - 1387-3806

VL - 216

SP - 85

EP - 93

JO - International Journal of Mass Spectrometry

JF - International Journal of Mass Spectrometry

IS - 1-2

ER -

Collision-induced dissociation of lanthanide oxide ions in quadrupole ion traps: Effects of bond strength and mass

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