Co(II) and Mn(II) complexes of 2,2'-thiodiethanol: [Co(II)(2,2'-thiodiethanol)2Cl2] and [Mn(2,2'thiodiethanol)Cl2](n)

Y. Zhang; S. Wang; C. Bridges; J. E. Greedan

doi:10.1139/cjc-78-10-1289

Co(II) and Mn(II) complexes of 2,2'-thiodiethanol: [Co(II)(2,2'-thiodiethanol)₂Cl₂] and [Mn(2,2'thiodiethanol)Cl₂](n)

Y. Zhang, S. Wang, C. Bridges, J. E. Greedan

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

[Co(2,2'-thiodiethanol)₂Cl₂] (1) and [Mn(2,2'-thiodiethanol)Cl₂](n) (2), have been synthesized and characterized structurally. Compound 1 is a six-coordinate, mononuclear Co(II) complex. The mononuclear units in the crystal lattice of 1 are linked together through intermolecular hydrogen bonds between hydroxy and chloride groups to form a three-dimensional array. Compound 2 consists of six-coordinate Mn(II) units that are linked by covalently bound 2,2'thiodiethanol and chloride ligands to form an alternating one-dimensional chain, which is further linked together by inter-chain hydrogen bonds to form a two-dimensional sheet. Antiferromagnetic exchange is present in compound 2.

Original language	English
Pages (from-to)	1289-1294
Number of pages	6
Journal	Canadian Journal of Chemistry
Volume	78
Issue number	10
DOIs	https://doi.org/10.1139/cjc-78-10-1289
State	Published - 2000
Externally published	Yes

Keywords

2,2'-thiodiethanol
Cobalt
Magnetism
Manganese
Structure

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10.1139/cjc-78-10-1289

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title = "Co(II) and Mn(II) complexes of 2,2'-thiodiethanol: [Co(II)(2,2'-thiodiethanol)2Cl2] and [Mn(2,2'thiodiethanol)Cl2](n)",

abstract = "[Co(2,2'-thiodiethanol)2Cl2] (1) and [Mn(2,2'-thiodiethanol)Cl2](n) (2), have been synthesized and characterized structurally. Compound 1 is a six-coordinate, mononuclear Co(II) complex. The mononuclear units in the crystal lattice of 1 are linked together through intermolecular hydrogen bonds between hydroxy and chloride groups to form a three-dimensional array. Compound 2 consists of six-coordinate Mn(II) units that are linked by covalently bound 2,2'thiodiethanol and chloride ligands to form an alternating one-dimensional chain, which is further linked together by inter-chain hydrogen bonds to form a two-dimensional sheet. Antiferromagnetic exchange is present in compound 2.",

keywords = "2,2'-thiodiethanol, Cobalt, Magnetism, Manganese, Structure",

author = "Y. Zhang and S. Wang and C. Bridges and Greedan, {J. E.}",

year = "2000",

doi = "10.1139/cjc-78-10-1289",

language = "English",

volume = "78",

pages = "1289--1294",

journal = "Canadian Journal of Chemistry",

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publisher = "Canadian Science Publishing",

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TY - JOUR

T1 - Co(II) and Mn(II) complexes of 2,2'-thiodiethanol

T2 - [Co(II)(2,2'-thiodiethanol)2Cl2] and [Mn(2,2'thiodiethanol)Cl2](n)

AU - Zhang, Y.

AU - Wang, S.

AU - Bridges, C.

AU - Greedan, J. E.

PY - 2000

Y1 - 2000

N2 - [Co(2,2'-thiodiethanol)2Cl2] (1) and [Mn(2,2'-thiodiethanol)Cl2](n) (2), have been synthesized and characterized structurally. Compound 1 is a six-coordinate, mononuclear Co(II) complex. The mononuclear units in the crystal lattice of 1 are linked together through intermolecular hydrogen bonds between hydroxy and chloride groups to form a three-dimensional array. Compound 2 consists of six-coordinate Mn(II) units that are linked by covalently bound 2,2'thiodiethanol and chloride ligands to form an alternating one-dimensional chain, which is further linked together by inter-chain hydrogen bonds to form a two-dimensional sheet. Antiferromagnetic exchange is present in compound 2.

AB - [Co(2,2'-thiodiethanol)2Cl2] (1) and [Mn(2,2'-thiodiethanol)Cl2](n) (2), have been synthesized and characterized structurally. Compound 1 is a six-coordinate, mononuclear Co(II) complex. The mononuclear units in the crystal lattice of 1 are linked together through intermolecular hydrogen bonds between hydroxy and chloride groups to form a three-dimensional array. Compound 2 consists of six-coordinate Mn(II) units that are linked by covalently bound 2,2'thiodiethanol and chloride ligands to form an alternating one-dimensional chain, which is further linked together by inter-chain hydrogen bonds to form a two-dimensional sheet. Antiferromagnetic exchange is present in compound 2.

KW - 2,2'-thiodiethanol

KW - Cobalt

KW - Magnetism

KW - Manganese

KW - Structure

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U2 - 10.1139/cjc-78-10-1289

DO - 10.1139/cjc-78-10-1289

M3 - Article

AN - SCOPUS:0033673002

SN - 0008-4042

VL - 78

SP - 1289

EP - 1294

JO - Canadian Journal of Chemistry

JF - Canadian Journal of Chemistry

IS - 10

ER -

Co(II) and Mn(II) complexes of 2,2'-thiodiethanol: [Co(II)(2,2'-thiodiethanol)₂Cl₂] and [Mn(2,2'thiodiethanol)Cl₂](n)

Abstract

Keywords

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