Coexistence of two structural relaxation processes in monohydroxy alcohol-alkyl halogen mixtures: Dielectric and rheological studies

Evidence for the existence of two glass transitions is found in binary mixtures of monohydroxy alcohols with an aprotic alkyl halide by means of dielectric spectroscopy and, markedly, also shear rheology. In the mechanical data, an enormous separation of two components becomes obvious for suitable compositions. The observation of bimodal motional heterogeneity is possible despite the fact that the glass transition temperatures of these substances differ by only 40 K. Obviously, the hydrogen-bond driven formation of supramolecular structures in one of the mixture components facilitates the emergence of dynamic contrast which for other binary liquids was so far only observed in the presence of much larger glass transition temperature differences.