Coarsening kinetics of coherent γ′ precipitates in ternary Ni-based alloys: The Ni-Al-Si system

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Abstract

Coarsening of coherent precipitates γ′ in alloys such as Ni-based alloys has been studied extensively not only for its practical significance in the design of engineering alloys but also in an effort to understand the phenomenon of coarsening. However, a complete understanding of the role of the multiple factors that can affect the coarsening kinetics in such systems is still lacking. Although some advances have been made through computer simulations, studying experimentally the influence of the volume fraction of the second phase and that of coherency strains on the kinetics of coarsening has been particularly challenging. This paper will highlight some of the issues that are relevant to the study of coarsening in multi-component alloy systems. Recent results obtained for the kinetics of coarsening of γ′ precipitates in different alloys within the Ni-Al-Si system will be presented. Compositions of these alloys have been chosen so as to vary both the magnitude and the sign of coherency strains between the precipitate and the matrix. Some anomalies related to the composition dependence of the kinetics of coarsening will be highlighted. This paper will conclude with a discussion on the role of the volume fraction of the second phase and coherency strains in contributing to these anomalies and identify directions for future work.

Original languageEnglish
Pages (from-to)51-62
Number of pages12
JournalScience and Technology of Advanced Materials
Volume1
Issue number1
DOIs
StatePublished - Mar 2000

Funding

One of the authors (G.M.) would like to thank Denis Wozniak for his help with the processing of the alloys and data collection, and Dr P. Thiyagarajan for his help with SANS measurements. The Argonne National Laboratory part of this work was supported by the US Department of Energy, Division of Materials Sciences, Office of Basic Energy Sciences under contract No. W-31-109-ENG-38. Work at the University of Illinois was funded by the Department of Energy through the Materials Research Laboratory under contract No. DEFG02-96ER45439.

FundersFunder number
Materials Research Laboratory
Office of Basic Energy Sciences
US Department of Energy
U.S. Department of Energy
Argonne National Laboratory
Division of Materials Sciences and Engineering

    Keywords

    • Coarsening kinetics
    • Coherency strains
    • Intermetallic compounds
    • Ni-based superalloys
    • Small-angle neutron scattering

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