Co-catalyzed Hydrogenation of Levulinic Acid to γ-Valerolactone under Atmospheric Pressure

Zhenghui Liu; Zhenzhen Yang; Peng Wang; Xiaoxiao Yu; Yunyan Wu; Huan Wang; Zhimin Liu

doi:10.1021/acssuschemeng.9b04803

Co-catalyzed Hydrogenation of Levulinic Acid to γ-Valerolactone under Atmospheric Pressure

Zhenghui Liu, Zhenzhen Yang, Peng Wang, Xiaoxiao Yu, Yunyan Wu, Huan Wang, Zhimin Liu

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

A cobalt-based catalytic system composed of Co(BF₄)₂·6H₂O and ligand P(CH₂CH₂PPh₂)₃ was developed for hydrogenation of levulinic acid to γ-valerolactone (GVL), which showed high efficiency for this reaction, affording a GVL yield of 95% under atmospheric pressure and 100 °C.

Original language	English
Pages (from-to)	18236-18241
Number of pages	6
Journal	ACS Sustainable Chemistry and Engineering
Volume	7
Issue number	22
DOIs	https://doi.org/10.1021/acssuschemeng.9b04803
State	Published - Nov 18 2019
Externally published	Yes

Funding

This work was financially supported by Chinese Academy of Sciences (Grant No. QYZDY-SSW-SLH013) and Beijing Munic ipal Science & Technology Commission (No. Z191100007219009). This work was financially supported by Chinese Academy of Sciences (Grant No. QYZDY-SSW-SLH013) and Beijing Munic ipal Science & Technology Commission (No. Z191100007219009).

Funders	Funder number
Beijing Munic ipal Science & Technology Commission	Z191100007219009
Chinese Academy of Sciences	QYZDY-SSW-SLH013

Keywords

Cobalt catalyst
Homogeneous catalysis
Hydrogenation
Levulinic acid
γ-Valerolactone

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10.1021/acssuschemeng.9b04803

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title = "Co-catalyzed Hydrogenation of Levulinic Acid to γ-Valerolactone under Atmospheric Pressure",

abstract = "A cobalt-based catalytic system composed of Co(BF4)2·6H2O and ligand P(CH2CH2PPh2)3 was developed for hydrogenation of levulinic acid to γ-valerolactone (GVL), which showed high efficiency for this reaction, affording a GVL yield of 95% under atmospheric pressure and 100 °C.",

keywords = "Cobalt catalyst, Homogeneous catalysis, Hydrogenation, Levulinic acid, γ-Valerolactone",

author = "Zhenghui Liu and Zhenzhen Yang and Peng Wang and Xiaoxiao Yu and Yunyan Wu and Huan Wang and Zhimin Liu",

note = "Publisher Copyright: Copyright {\textcopyright} 2019 American Chemical Society.",

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day = "18",

doi = "10.1021/acssuschemeng.9b04803",

language = "English",

volume = "7",

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journal = "ACS Sustainable Chemistry and Engineering",

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T1 - Co-catalyzed Hydrogenation of Levulinic Acid to γ-Valerolactone under Atmospheric Pressure

AU - Liu, Zhenghui

AU - Yang, Zhenzhen

AU - Wang, Peng

AU - Yu, Xiaoxiao

AU - Wu, Yunyan

AU - Wang, Huan

AU - Liu, Zhimin

PY - 2019/11/18

Y1 - 2019/11/18

N2 - A cobalt-based catalytic system composed of Co(BF4)2·6H2O and ligand P(CH2CH2PPh2)3 was developed for hydrogenation of levulinic acid to γ-valerolactone (GVL), which showed high efficiency for this reaction, affording a GVL yield of 95% under atmospheric pressure and 100 °C.

AB - A cobalt-based catalytic system composed of Co(BF4)2·6H2O and ligand P(CH2CH2PPh2)3 was developed for hydrogenation of levulinic acid to γ-valerolactone (GVL), which showed high efficiency for this reaction, affording a GVL yield of 95% under atmospheric pressure and 100 °C.

KW - Cobalt catalyst

KW - Homogeneous catalysis

KW - Hydrogenation

KW - Levulinic acid

KW - γ-Valerolactone

UR - http://www.scopus.com/inward/record.url?scp=85074706238&partnerID=8YFLogxK

U2 - 10.1021/acssuschemeng.9b04803

DO - 10.1021/acssuschemeng.9b04803

M3 - Article

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SP - 18236

EP - 18241

JO - ACS Sustainable Chemistry and Engineering

JF - ACS Sustainable Chemistry and Engineering

IS - 22

ER -

Co-catalyzed Hydrogenation of Levulinic Acid to γ-Valerolactone under Atmospheric Pressure

Abstract

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