Chromatographic separation of selenium and arsenic: A potential 72Se/72As generator

Donald E. Wycoff; Matthew D. Gott; Anthony J. DeGraffenreid; Ryan P. Morrow; Nebiat Sisay; Mary F. Embree; Beau Ballard; Michael E. Fassbender; Cathy S. Cutler; Alan R. Ketring; Silvia S. Jurisson

doi:10.1016/j.chroma.2014.03.033

Chromatographic separation of selenium and arsenic: A potential ⁷²Se/⁷²As generator

Donald E. Wycoff
, Matthew D. Gott
, Anthony J. DeGraffenreid
, Ryan P. Morrow
, Nebiat Sisay
, Mary F. Embree
, Beau Ballard
, Michael E. Fassbender
, Cathy S. Cutler
, Alan R. Ketring
, Silvia S. Jurisson

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

An anion exchange method was developed to separate selenium and arsenic for potential utility in a ⁷²Se/⁷²As generator. The separation of the daughter ⁷²As from the ⁷²Se parent is based on the relative acid-base behavior of the two oxo-anions in their highest oxidation states. At pH 1.5, selenate is retained on strongly basic anion exchange resin as HSeO₄^- and SeO₄^2-, while neutral arsenic acid, H₃AsO₄, is eluted.

Original language	English
Pages (from-to)	109-114
Number of pages	6
Journal	Journal of Chromatography A
Volume	1340
DOIs	https://doi.org/10.1016/j.chroma.2014.03.033
State	Published - May 2 2014
Externally published	Yes

Funding

The authors acknowledge support from the Department of Energy, Office of Basic Energy Sciences, Isotope Research program under Grant No. DE-SC0003851, and trainee support from the National Science Foundation under IGERT award DGE-0965983 (M.D. Gott) and NIBIB Training Grant NIBIB 5 T32 EB004822 (A.J. DeGraffenreid). The 72 Se production was funded by the United States Department of Energy, Office of Science via an award from the Isotope Development and Production for Research and Applications subprogram in the Office of Nuclear Physics.

Keywords

As-72
Ion exchange
Radionuclide generator
Se-72

Access to Document

10.1016/j.chroma.2014.03.033

Cite this

@article{0a90c7c712d44151899fe2bd1bb4dc70,

title = "Chromatographic separation of selenium and arsenic: A potential 72Se/72As generator",

abstract = "An anion exchange method was developed to separate selenium and arsenic for potential utility in a 72Se/72As generator. The separation of the daughter 72As from the 72Se parent is based on the relative acid-base behavior of the two oxo-anions in their highest oxidation states. At pH 1.5, selenate is retained on strongly basic anion exchange resin as HSeO4- and SeO42-, while neutral arsenic acid, H3AsO4, is eluted.",

keywords = "As-72, Ion exchange, Radionuclide generator, Se-72",

author = "Wycoff, \{Donald E.\} and Gott, \{Matthew D.\} and DeGraffenreid, \{Anthony J.\} and Morrow, \{Ryan P.\} and Nebiat Sisay and Embree, \{Mary F.\} and Beau Ballard and Fassbender, \{Michael E.\} and Cutler, \{Cathy S.\} and Ketring, \{Alan R.\} and Jurisson, \{Silvia S.\}",

year = "2014",

month = may,

day = "2",

doi = "10.1016/j.chroma.2014.03.033",

language = "English",

volume = "1340",

pages = "109--114",

journal = "Journal of Chromatography A",

issn = "0021-9673",

publisher = "Elsevier",

}

TY - JOUR

T1 - Chromatographic separation of selenium and arsenic

T2 - A potential 72Se/72As generator

AU - Wycoff, Donald E.

AU - Gott, Matthew D.

AU - DeGraffenreid, Anthony J.

AU - Morrow, Ryan P.

AU - Sisay, Nebiat

AU - Embree, Mary F.

AU - Ballard, Beau

AU - Fassbender, Michael E.

AU - Cutler, Cathy S.

AU - Ketring, Alan R.

AU - Jurisson, Silvia S.

PY - 2014/5/2

Y1 - 2014/5/2

N2 - An anion exchange method was developed to separate selenium and arsenic for potential utility in a 72Se/72As generator. The separation of the daughter 72As from the 72Se parent is based on the relative acid-base behavior of the two oxo-anions in their highest oxidation states. At pH 1.5, selenate is retained on strongly basic anion exchange resin as HSeO4- and SeO42-, while neutral arsenic acid, H3AsO4, is eluted.

AB - An anion exchange method was developed to separate selenium and arsenic for potential utility in a 72Se/72As generator. The separation of the daughter 72As from the 72Se parent is based on the relative acid-base behavior of the two oxo-anions in their highest oxidation states. At pH 1.5, selenate is retained on strongly basic anion exchange resin as HSeO4- and SeO42-, while neutral arsenic acid, H3AsO4, is eluted.

KW - As-72

KW - Ion exchange

KW - Radionuclide generator

KW - Se-72

UR - https://www.scopus.com/pages/publications/84897960648

U2 - 10.1016/j.chroma.2014.03.033

DO - 10.1016/j.chroma.2014.03.033

M3 - Article

C2 - 24679827

AN - SCOPUS:84897960648

SN - 0021-9673

VL - 1340

SP - 109

EP - 114

JO - Journal of Chromatography A

JF - Journal of Chromatography A

ER -