Chemical preparation and crystal data for two new cyclotriphosphates M IIK4(P3O9)2 (MII=Co 2+ and Mn2+)

Kacem Sbai; Malika Tridane; Ali Abouimrane; Saïd Belaaouad; Abdelouahed Cherqaoui

doi:10.1154/1.1566954

Chemical preparation and crystal data for two new cyclotriphosphates M ^IIK₄(P₃O₉₎₂ (M^II=Co ²⁺ and Mn²⁺)

Kacem Sbai
, Malika Tridane
, Ali Abouimrane
, Saïd Belaaouad
, Abdelouahed Cherqaoui

Emerging and Solid-State Batteries

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Methods of chemical preparation and crystal data are reported for two new anhydrous cyclotriphosphates M^IIK₄(P₃O ₉₎₂ (M^IICo²⁺ and Mn²⁺). These anhydrous cyclotriphosphates CoK₄(P₃O₉₎₂ and MnK₄(P₃O₉₎₂ were obtained by total dehydration of corresponding hydrated cyclotriphosphates CoK₄(P₃O ₉₎₂.7H₂O and MnK₄P₃O ₉₎₂.2H₂O CoK₄(P₃O₉₎₂ is tridinic, space group P - 1, Z = 1 with the following unit-cell dimensions: a = 6.29(3) Å, b = 8.00(1)Å, c=13.05(8)Å, α=86.03(5)°, β= 98.00(1)°, γ=68.11(2)°. MnK₄(P ₃O₉₎₂ crystallizes in the rhombohedral system, space group P-3₁c, Z=2 with the following unit-cell dimensions: a = b = 7.337(3)Å, c= 19.920(1)Å.

Original language	English
Pages (from-to)	224-226
Number of pages	3
Journal	Powder Diffraction
Volume	18
Issue number	3
DOIs	https://doi.org/10.1154/1.1566954
State	Published - Sep 2003

Keywords

Anhydrous
Chemical preparation
Crystal data
Cyclotriphosphate
Powder diffraction

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10.1154/1.1566954

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@article{df343e036e3940bda7b8d6ac6301a80b,

title = "Chemical preparation and crystal data for two new cyclotriphosphates M IIK4(P3O9)2 (MII=Co 2+ and Mn2+)",

abstract = "Methods of chemical preparation and crystal data are reported for two new anhydrous cyclotriphosphates MIIK4(P3O 9)2 (MIICo2+ and Mn2+). These anhydrous cyclotriphosphates CoK4(P3O9)2 and MnK4(P3O9)2 were obtained by total dehydration of corresponding hydrated cyclotriphosphates CoK4(P3O 9)2.7H2O and MnK4P3O 9)2.2H2O CoK4(P3O9)2 is tridinic, space group P - 1, Z = 1 with the following unit-cell dimensions: a = 6.29(3) {\AA}, b = 8.00(1){\AA}, c=13.05(8){\AA}, α=86.03(5)°, β= 98.00(1)°, γ=68.11(2)°. MnK4(P 3O9)2 crystallizes in the rhombohedral system, space group P-31c, Z=2 with the following unit-cell dimensions: a = b = 7.337(3){\AA}, c= 19.920(1){\AA}.",

keywords = "Anhydrous, Chemical preparation, Crystal data, Cyclotriphosphate, Powder diffraction",

author = "Kacem Sbai and Malika Tridane and Ali Abouimrane and Sa{\"i}d Belaaouad and Abdelouahed Cherqaoui",

year = "2003",

month = sep,

doi = "10.1154/1.1566954",

language = "English",

volume = "18",

pages = "224--226",

journal = "Powder Diffraction",

issn = "0885-7156",

publisher = "Cambridge University Press",

number = "3",

}

TY - JOUR

T1 - Chemical preparation and crystal data for two new cyclotriphosphates M IIK4(P3O9)2 (MII=Co 2+ and Mn2+)

AU - Sbai, Kacem

AU - Tridane, Malika

AU - Abouimrane, Ali

AU - Belaaouad, Saïd

AU - Cherqaoui, Abdelouahed

PY - 2003/9

Y1 - 2003/9

N2 - Methods of chemical preparation and crystal data are reported for two new anhydrous cyclotriphosphates MIIK4(P3O 9)2 (MIICo2+ and Mn2+). These anhydrous cyclotriphosphates CoK4(P3O9)2 and MnK4(P3O9)2 were obtained by total dehydration of corresponding hydrated cyclotriphosphates CoK4(P3O 9)2.7H2O and MnK4P3O 9)2.2H2O CoK4(P3O9)2 is tridinic, space group P - 1, Z = 1 with the following unit-cell dimensions: a = 6.29(3) Å, b = 8.00(1)Å, c=13.05(8)Å, α=86.03(5)°, β= 98.00(1)°, γ=68.11(2)°. MnK4(P 3O9)2 crystallizes in the rhombohedral system, space group P-31c, Z=2 with the following unit-cell dimensions: a = b = 7.337(3)Å, c= 19.920(1)Å.

AB - Methods of chemical preparation and crystal data are reported for two new anhydrous cyclotriphosphates MIIK4(P3O 9)2 (MIICo2+ and Mn2+). These anhydrous cyclotriphosphates CoK4(P3O9)2 and MnK4(P3O9)2 were obtained by total dehydration of corresponding hydrated cyclotriphosphates CoK4(P3O 9)2.7H2O and MnK4P3O 9)2.2H2O CoK4(P3O9)2 is tridinic, space group P - 1, Z = 1 with the following unit-cell dimensions: a = 6.29(3) Å, b = 8.00(1)Å, c=13.05(8)Å, α=86.03(5)°, β= 98.00(1)°, γ=68.11(2)°. MnK4(P 3O9)2 crystallizes in the rhombohedral system, space group P-31c, Z=2 with the following unit-cell dimensions: a = b = 7.337(3)Å, c= 19.920(1)Å.

KW - Anhydrous

KW - Chemical preparation

KW - Crystal data

KW - Cyclotriphosphate

KW - Powder diffraction

UR - https://www.scopus.com/pages/publications/0141566335

U2 - 10.1154/1.1566954

DO - 10.1154/1.1566954

M3 - Article

AN - SCOPUS:0141566335

SN - 0885-7156

VL - 18

SP - 224

EP - 226

JO - Powder Diffraction

JF - Powder Diffraction

IS - 3

ER -

Chemical preparation and crystal data for two new cyclotriphosphates M ^IIK₄(P₃O₉₎₂ (M^II=Co ²⁺ and Mn²⁺)

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