Caustic-side solvent extraction chemical and physical properties: Equilibrium modeling of distribution behavior

Laetitia H. Delmau; Tamara J. Haverlock; Tatiana G. Levitskaia; Frederick V. Sloop; Bruce A. Moyer

Caustic-side solvent extraction chemical and physical properties: Equilibrium modeling of distribution behavior

Laetitia H. Delmau, Tamara J. Haverlock, Tatiana G. Levitskaia, Frederick V. Sloop, Bruce A. Moyer

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

Abstract

A multivariate mathematical model describing the extraction of cesium from different mixtures of sodium hydroxide, sodium nitrate, sodium chloride, and sodium nitrite containing potassium at variable concentrations has been established. It was determined based on the cesium, potassium, and sodium distribution ratios obtained with simple systems containing single salts. These experimental data were modeled to obtain the formation constants of complexes formed in the organic phase based on specified concentrations of components in both organic and aqueous phases. The model was applied to five different SRS waste simulants, and the corresponding cesium extraction results were predicted satisfactorily, thus validating the model.

Original language	English
Title of host publication	Physical Chemistry
Subtitle of host publication	Chemical Kinetics and Reaction Mechanisms
Publisher	Apple Academic Press
Pages	152-170
Number of pages	19
ISBN (Electronic)	9781466559813
ISBN (Print)	9781926692616
State	Published - Jan 1 2011

Cite this

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title = "Caustic-side solvent extraction chemical and physical properties: Equilibrium modeling of distribution behavior",

abstract = "A multivariate mathematical model describing the extraction of cesium from different mixtures of sodium hydroxide, sodium nitrate, sodium chloride, and sodium nitrite containing potassium at variable concentrations has been established. It was determined based on the cesium, potassium, and sodium distribution ratios obtained with simple systems containing single salts. These experimental data were modeled to obtain the formation constants of complexes formed in the organic phase based on specified concentrations of components in both organic and aqueous phases. The model was applied to five different SRS waste simulants, and the corresponding cesium extraction results were predicted satisfactorily, thus validating the model.",

author = "Delmau, {Laetitia H.} and Haverlock, {Tamara J.} and Levitskaia, {Tatiana G.} and Sloop, {Frederick V.} and Moyer, {Bruce A.}",

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year = "2011",

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Caustic-side solvent extraction chemical and physical properties: Equilibrium modeling of distribution behavior. / Delmau, Laetitia H.; Haverlock, Tamara J.; Levitskaia, Tatiana G. et al.
Physical Chemistry: Chemical Kinetics and Reaction Mechanisms. Apple Academic Press, 2011. p. 152-170.

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

TY - CHAP

T1 - Caustic-side solvent extraction chemical and physical properties

T2 - Equilibrium modeling of distribution behavior

AU - Delmau, Laetitia H.

AU - Haverlock, Tamara J.

AU - Levitskaia, Tatiana G.

AU - Sloop, Frederick V.

AU - Moyer, Bruce A.

PY - 2011/1/1

Y1 - 2011/1/1

N2 - A multivariate mathematical model describing the extraction of cesium from different mixtures of sodium hydroxide, sodium nitrate, sodium chloride, and sodium nitrite containing potassium at variable concentrations has been established. It was determined based on the cesium, potassium, and sodium distribution ratios obtained with simple systems containing single salts. These experimental data were modeled to obtain the formation constants of complexes formed in the organic phase based on specified concentrations of components in both organic and aqueous phases. The model was applied to five different SRS waste simulants, and the corresponding cesium extraction results were predicted satisfactorily, thus validating the model.

AB - A multivariate mathematical model describing the extraction of cesium from different mixtures of sodium hydroxide, sodium nitrate, sodium chloride, and sodium nitrite containing potassium at variable concentrations has been established. It was determined based on the cesium, potassium, and sodium distribution ratios obtained with simple systems containing single salts. These experimental data were modeled to obtain the formation constants of complexes formed in the organic phase based on specified concentrations of components in both organic and aqueous phases. The model was applied to five different SRS waste simulants, and the corresponding cesium extraction results were predicted satisfactorily, thus validating the model.

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M3 - Chapter

AN - SCOPUS:85059572711

SN - 9781926692616

SP - 152

EP - 170

BT - Physical Chemistry

PB - Apple Academic Press

ER -

Caustic-side solvent extraction chemical and physical properties: Equilibrium modeling of distribution behavior

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