Cation-Anion Redox Switching in an All-Ferrocene Salt

Briana R. Schrage; Zhiling Zhao; Christopher J. Ziegler; Aliaksei Boika

doi:10.1002/celc.201801035

Cation-Anion Redox Switching in an All-Ferrocene Salt

Briana R. Schrage, Zhiling Zhao, Christopher J. Ziegler, Aliaksei Boika

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

An “all-ferrocene” salt comprised of two ferrocene cations and one ferrocene dianion exhibits an unusual reversing of oxidation-reduction potentials between the cationic and the anionic components. This redox switching can be controlled via the solvent, and is not greatly affected by the supporting electrolyte.

Original language	English
Pages (from-to)	3624-3627
Number of pages	4
Journal	ChemElectroChem
Volume	5
Issue number	23
DOIs	https://doi.org/10.1002/celc.201801035
State	Published - Dec 3 2018
Externally published	Yes

Funding

We acknowledge The University of Akron and the National Science Foundation (CHE-1665267) for support of this research.

Funders	Funder number
National Science Foundation	CHE-1665267, 1665267
University of Akron

Keywords

DMF-water mixture
X-ray diffraction
cyclic voltammetry
ferrocene
metathesis

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10.1002/celc.201801035

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title = "Cation-Anion Redox Switching in an All-Ferrocene Salt",

abstract = "An “all-ferrocene” salt comprised of two ferrocene cations and one ferrocene dianion exhibits an unusual reversing of oxidation-reduction potentials between the cationic and the anionic components. This redox switching can be controlled via the solvent, and is not greatly affected by the supporting electrolyte.",

keywords = "DMF-water mixture, X-ray diffraction, cyclic voltammetry, ferrocene, metathesis",

author = "Schrage, {Briana R.} and Zhiling Zhao and Ziegler, {Christopher J.} and Aliaksei Boika",

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AU - Schrage, Briana R.

AU - Zhao, Zhiling

AU - Ziegler, Christopher J.

AU - Boika, Aliaksei

PY - 2018/12/3

Y1 - 2018/12/3

N2 - An “all-ferrocene” salt comprised of two ferrocene cations and one ferrocene dianion exhibits an unusual reversing of oxidation-reduction potentials between the cationic and the anionic components. This redox switching can be controlled via the solvent, and is not greatly affected by the supporting electrolyte.

AB - An “all-ferrocene” salt comprised of two ferrocene cations and one ferrocene dianion exhibits an unusual reversing of oxidation-reduction potentials between the cationic and the anionic components. This redox switching can be controlled via the solvent, and is not greatly affected by the supporting electrolyte.

KW - DMF-water mixture

KW - X-ray diffraction

KW - cyclic voltammetry

KW - ferrocene

KW - metathesis

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Cation-Anion Redox Switching in an All-Ferrocene Salt

Abstract

Funding

Keywords

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