Catalytic chemistry on oxide nanostructures

Aravind Asthagiri; David A. Dixon; Zdenek Dohnálek; Bruce D. Kay; José A. Rodriguez; Roger Rousseau; Darío J. Stacchiola; Jason F. Weaver

doi:10.1007/978-3-319-28332-6_9

Catalytic chemistry on oxide nanostructures

Aravind Asthagiri, David A. Dixon, Zdenek Dohnálek, Bruce D. Kay, José A. Rodriguez, Roger Rousseau, Darío J. Stacchiola, Jason F. Weaver

Chemical Sciences Division

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

2 Scopus citations

Abstract

In this chapter we review distinct well-defined planar models to illustrate the unique chemical properties that can be realized by oxide nanostructuring in the form of continuous ultra-thin films, extended islands and/or supported nanoclusters. The highlighted systems include metastable PdO films for C–H bond activation, multifunctional catalytic sites at copper/cerium-oxide island interfaces for water-gas shift reactions, and (WO₃)₃ and (MoO₃)₃ nanoclusters with active dioxo, O=M=O, moieties for dehydration and partial oxidation of alcohols.

Original language	English
Title of host publication	Springer Series in Materials Science
Publisher	Springer Verlag
Pages	251-280
Number of pages	30
DOIs	https://doi.org/10.1007/978-3-319-28332-6_9
State	Published - Apr 1 2016

Publication series

Name	Springer Series in Materials Science
Volume	234
ISSN (Print)	0933-033X

Funding

The authors acknowledge support from the U.S. Department of Energy, Office of Science, Basic Energy Sciences, Chemical Sciences, Geosciences, and Biosciences Division under contracts DE-FG02-03ER15478 (AA and JFW), DE-SC0012704 (JAR and DJS), and DE-AC06-76RLO 1830 (DAD, ZD, BDK and RR). PNNL is operated for the U.S. DOE by Battelle Memorial Institute. AA and JFW acknowledge the Ohio Supercomputing Center for providing computational resources. DAD is indebted to the Robert Ramsay Endowment of The University of Alabama for partial support.

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AU - Asthagiri, Aravind

AU - Dixon, David A.

AU - Dohnálek, Zdenek

AU - Kay, Bruce D.

AU - Rodriguez, José A.

AU - Rousseau, Roger

AU - Stacchiola, Darío J.

AU - Weaver, Jason F.

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EP - 280

BT - Springer Series in Materials Science

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Catalytic chemistry on oxide nanostructures

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