Catalysis of Diene Polymerization and Diels-Alder Reactions by an Octahedral Tungsten Nitrosyl Lewis Acid. X-ray Crystal Structure of the η1-Acrolein Complex (cis-Me3p)trans-NO)(CO)3W̶O═C(H)C(H)═CH2

Robert V. Honevchuck; Peter V. Bonnesen; Judah Farahi; William H. Hersh

doi:10.1021/jo00232a049

Catalysis of Diene Polymerization and Diels-Alder Reactions by an Octahedral Tungsten Nitrosyl Lewis Acid. X-ray Crystal Structure of the η¹-Acrolein Complex (cis-Me₃p)trans-NO)(CO)₃W̶O═C(H)C(H)═CH₂

Robert V. Honevchuck
, Peter V. Bonnesen
, Judah Farahi
, William H. Hersh

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

Cyclopentadiene and isoprene are polymerized by 0.1 mol % (Me₃P)(CO)₃(NO)W-FSbF₅(1), and catalysis of the Diels-Alder reactions of cyclopentadiene or butadiene with α,β-unsaturated enones is also induced by as little as 0.1 mol % 1; the X-ray structure of the adduct of 1 and acrolein, the presumed catalytic intermediate, reveals a simple Lewis acid interaction of the tungsten with the acrolein oxygen.

Original language	English
Pages (from-to)	5293-5296
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	52
Issue number	23
DOIs	https://doi.org/10.1021/jo00232a049
State	Published - Nov 1 1987
Externally published	Yes

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@article{d3771745101749a0940d7ed7dc5f724f,

title = "Catalysis of Diene Polymerization and Diels-Alder Reactions by an Octahedral Tungsten Nitrosyl Lewis Acid. X-ray Crystal Structure of the η1-Acrolein Complex (cis-Me3p)trans-NO)(CO)3W̶O═C(H)C(H)═CH2",

abstract = "Cyclopentadiene and isoprene are polymerized by 0.1 mol \% (Me3P)(CO)3(NO)W-FSbF5(1), and catalysis of the Diels-Alder reactions of cyclopentadiene or butadiene with α,β-unsaturated enones is also induced by as little as 0.1 mol \% 1; the X-ray structure of the adduct of 1 and acrolein, the presumed catalytic intermediate, reveals a simple Lewis acid interaction of the tungsten with the acrolein oxygen.",

author = "Honevchuck, \{Robert V.\} and Bonnesen, \{Peter V.\} and Judah Farahi and Hersh, \{William H.\}",

year = "1987",

month = nov,

day = "1",

doi = "10.1021/jo00232a049",

language = "English",

volume = "52",

pages = "5293--5296",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "23",

}

Catalysis of Diene Polymerization and Diels-Alder Reactions by an Octahedral Tungsten Nitrosyl Lewis Acid. X-ray Crystal Structure of the η¹-Acrolein Complex (cis-Me₃p)trans-NO)(CO)₃W̶O═C(H)C(H)═CH₂. / Honevchuck, Robert V.; Bonnesen, Peter V.; Farahi, Judah et al.
In: Journal of Organic Chemistry, Vol. 52, No. 23, 01.11.1987, p. 5293-5296.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Catalysis of Diene Polymerization and Diels-Alder Reactions by an Octahedral Tungsten Nitrosyl Lewis Acid. X-ray Crystal Structure of the η1-Acrolein Complex (cis-Me3p)trans-NO)(CO)3W̶O═C(H)C(H)═CH2

AU - Honevchuck, Robert V.

AU - Bonnesen, Peter V.

AU - Farahi, Judah

AU - Hersh, William H.

PY - 1987/11/1

Y1 - 1987/11/1

N2 - Cyclopentadiene and isoprene are polymerized by 0.1 mol % (Me3P)(CO)3(NO)W-FSbF5(1), and catalysis of the Diels-Alder reactions of cyclopentadiene or butadiene with α,β-unsaturated enones is also induced by as little as 0.1 mol % 1; the X-ray structure of the adduct of 1 and acrolein, the presumed catalytic intermediate, reveals a simple Lewis acid interaction of the tungsten with the acrolein oxygen.

AB - Cyclopentadiene and isoprene are polymerized by 0.1 mol % (Me3P)(CO)3(NO)W-FSbF5(1), and catalysis of the Diels-Alder reactions of cyclopentadiene or butadiene with α,β-unsaturated enones is also induced by as little as 0.1 mol % 1; the X-ray structure of the adduct of 1 and acrolein, the presumed catalytic intermediate, reveals a simple Lewis acid interaction of the tungsten with the acrolein oxygen.

UR - https://www.scopus.com/pages/publications/0001135864

U2 - 10.1021/jo00232a049

DO - 10.1021/jo00232a049

M3 - Article

AN - SCOPUS:0001135864

SN - 0022-3263

VL - 52

SP - 5293

EP - 5296

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 23