Catalysis for hydrogen storage

John C. Linehan; Tom Autrey; John L. Fulton; Yongsheng Chen; Mahalingam Balasubramanian

Catalysis for hydrogen storage

John C. Linehan
, Tom Autrey
, John L. Fulton
, Yongsheng Chen
, Mahalingam Balasubramanian

Emerging and Solid-State Batteries

Research output: Contribution to journal › Conference article › peer-review

Abstract

DOE recently issued a Grand Challenge in Hydrogen Storage. In response to this call, there has been a recent concerted call from the scientific community for intensive fundamental studies to develop new approaches and novel materials for hydrogen fuel cells, hydrogen production, and storage to move the energy economy from one based on fossil fuels to one based upon hydrogen. In situ XAFS, NMR, and IR spectroscopies were applied to study the transition metal-catalyzed H₂ release from ammonia boranes. These methods allowed real time interrogations of substrates, products and catalysts yielding kinetics and mechanistic information not possible with ex situ techniques. The release of H₂ from NH₃BH₃, Me₂NHBH₃, and (iPr)₂NHBH₃ was studied using rhodium and ruthenium-based catalysts. Mechanistic differences between thermal and catalyzed H₂ release were observed. This is an abstract of a paper presented at the 230th ACS National Meeting (Washington, DC 8/28/2005-9/1/2005).

Original language	English
Journal	ACS National Meeting Book of Abstracts
Volume	230
State	Published - 2005
Event	230th ACS National Meeting - Washington, DC, United States Duration: Aug 28 2005 → Sep 1 2005

Cite this

@article{85f0d7aeeb554898bb3bd9ace1d1f95c,

title = "Catalysis for hydrogen storage",

abstract = "DOE recently issued a Grand Challenge in Hydrogen Storage. In response to this call, there has been a recent concerted call from the scientific community for intensive fundamental studies to develop new approaches and novel materials for hydrogen fuel cells, hydrogen production, and storage to move the energy economy from one based on fossil fuels to one based upon hydrogen. In situ XAFS, NMR, and IR spectroscopies were applied to study the transition metal-catalyzed H2 release from ammonia boranes. These methods allowed real time interrogations of substrates, products and catalysts yielding kinetics and mechanistic information not possible with ex situ techniques. The release of H2 from NH3BH3, Me2NHBH3, and (iPr)2NHBH3 was studied using rhodium and ruthenium-based catalysts. Mechanistic differences between thermal and catalyzed H2 release were observed. This is an abstract of a paper presented at the 230th ACS National Meeting (Washington, DC 8/28/2005-9/1/2005).",

author = "Linehan, \{John C.\} and Tom Autrey and Fulton, \{John L.\} and Yongsheng Chen and Mahalingam Balasubramanian",

year = "2005",

language = "English",

volume = "230",

journal = "ACS National Meeting Book of Abstracts",

issn = "0065-7727",

note = "230th ACS National Meeting ; Conference date: 28-08-2005 Through 01-09-2005",

}

TY - JOUR

T1 - Catalysis for hydrogen storage

AU - Linehan, John C.

AU - Autrey, Tom

AU - Fulton, John L.

AU - Chen, Yongsheng

AU - Balasubramanian, Mahalingam

PY - 2005

Y1 - 2005

N2 - DOE recently issued a Grand Challenge in Hydrogen Storage. In response to this call, there has been a recent concerted call from the scientific community for intensive fundamental studies to develop new approaches and novel materials for hydrogen fuel cells, hydrogen production, and storage to move the energy economy from one based on fossil fuels to one based upon hydrogen. In situ XAFS, NMR, and IR spectroscopies were applied to study the transition metal-catalyzed H2 release from ammonia boranes. These methods allowed real time interrogations of substrates, products and catalysts yielding kinetics and mechanistic information not possible with ex situ techniques. The release of H2 from NH3BH3, Me2NHBH3, and (iPr)2NHBH3 was studied using rhodium and ruthenium-based catalysts. Mechanistic differences between thermal and catalyzed H2 release were observed. This is an abstract of a paper presented at the 230th ACS National Meeting (Washington, DC 8/28/2005-9/1/2005).

AB - DOE recently issued a Grand Challenge in Hydrogen Storage. In response to this call, there has been a recent concerted call from the scientific community for intensive fundamental studies to develop new approaches and novel materials for hydrogen fuel cells, hydrogen production, and storage to move the energy economy from one based on fossil fuels to one based upon hydrogen. In situ XAFS, NMR, and IR spectroscopies were applied to study the transition metal-catalyzed H2 release from ammonia boranes. These methods allowed real time interrogations of substrates, products and catalysts yielding kinetics and mechanistic information not possible with ex situ techniques. The release of H2 from NH3BH3, Me2NHBH3, and (iPr)2NHBH3 was studied using rhodium and ruthenium-based catalysts. Mechanistic differences between thermal and catalyzed H2 release were observed. This is an abstract of a paper presented at the 230th ACS National Meeting (Washington, DC 8/28/2005-9/1/2005).

UR - https://www.scopus.com/pages/publications/33745398380

M3 - Conference article

AN - SCOPUS:33745398380

SN - 0065-7727

VL - 230

JO - ACS National Meeting Book of Abstracts

JF - ACS National Meeting Book of Abstracts

T2 - 230th ACS National Meeting

Y2 - 28 August 2005 through 1 September 2005

ER -

Catalysis for hydrogen storage

Abstract

Other files and links

Fingerprint

Cite this