CARS spectra of thermally excited SF6 molecules

A. A. Puretzky, V. N. Zadkov

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

CARS spectra of the v1 mode of thermally excited SF6 were calculated numerically. The influence of the vibrational quasicontinuum on the CARS spectra has been considered by introducing different types of the homogeneous broadening at different vibrational levels. The appearance of additional lines in the CARS spectrum due to mixing of high-lying vibrational levels by Fermi coupling was considered numerically in the frame of a simple model. A comparison of calculated and experimental spectra has been made.

Original languageEnglish
Pages (from-to)89-96
Number of pages8
JournalApplied Physics B Photophysics and Laser Chemistry
Volume31
Issue number2
DOIs
StatePublished - Jun 1983
Externally publishedYes

Keywords

  • 33
  • 82.50

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