Carbon nitride nanothread crystals derived from pyridine

Xiang Li; Tao Wang; Pu Duan; Maria Baldini; Haw Tyng Huang; Bo Chen; Stephen J. Juhl; Daniel Koeplinger; Vincent H. Crespi; Klaus Schmidt-Rohr; Roald Hoffmann; Nasim Alem; Malcolm Guthrie; Xin Zhang; John V. Badding

doi:10.1021/jacs.7b13247

Carbon nitride nanothread crystals derived from pyridine

Xiang Li, Tao Wang, Pu Duan, Maria Baldini, Haw Tyng Huang, Bo Chen, Stephen J. Juhl, Daniel Koeplinger, Vincent H. Crespi, Klaus Schmidt-Rohr, Roald Hoffmann, Nasim Alem, Malcolm Guthrie, Xin Zhang, John V. Badding

Research output: Contribution to journal › Article › peer-review

85 Scopus citations

Abstract

Carbon nanothreads are a new one-dimensional sp³ carbon nanomaterial. They assemble into hexagonal crystals in a room temperature, nontopochemical solid-state reaction induced by slow compression of benzene to 23 GPa. Here we show that pyridine also reacts under compression to form a well-ordered sp³ product: C₅NH₅ carbon nitride nanothreads. Solid pyridine has a different crystal structure from solid benzene, so the nontopochemical formation of low-dimensional crystalline solids by slow compression of small aromatics may be a general phenomenon that enables chemical design of properties. The nitrogen in the carbon nitride nanothreads may improve processability, alters photoluminescence, and is predicted to reduce the bandgap.

Original language	English
Pages (from-to)	4969-4972
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	140
Issue number	15
DOIs	https://doi.org/10.1021/jacs.7b13247
State	Published - Apr 18 2018
Externally published	Yes

Funding

We acknowledge the Energy Frontier Research in Extreme Environments (EFree) Center, an Energy Frontier Research Center, funded by the Department of Energy (DOE) Office of Science (DE-SC0001057). Samples were synthesized at the Spallation Neutrons and Pressure beamline (SNAP) at the Spallation Neutron Source, a DOE Office of Science User Facility operated by Oak Ridge National Laboratory and the High-Pressure Neutron Diffractometer beamline (PLANET) at the Japan Proton Accelerator Research Complex. X-ray diffraction was performed at the High-Pressure Collaborative Access Team (HPCAT) beamlines 16 BM-D and 16 ID-B at the Advanced Photon Source (APS), Argonne National Laboratory. HPCAT is supported by DOE-NNSA (DE-NA0007), with partial instrumentation support from the National Science Foundation. We thank C. Park and H. We acknowledge the Energy Frontier Research in Extreme Environments (EFree) Center, an Energy Frontier Research Center, funded by the Department of Energy (DOE) Office of Science (DE-SC0001057). Samples were synthesized at the Spallation Neutrons and Pressure beamline (SNAP) at the Spallation Neutron Source, a DOE Office of Science User Facility operated by Oak Ridge National Laboratory and the High-Pressure Neutron Diffractometer beamline (PLANET) at the Japan Proton Accelerator Research Complex. X-ray diffraction was performed at the High-Pressure Collaborative Access Team (HPCAT) beamlines 16 BM-D and 16 ID-B at the Advanced Photon Source (APS), Argonne National Laboratory. HPCAT is supported by DOE-NNSA (DE-NA0007), with partial instrumentation support from the National Science Foundation. We thank C. Park and H. Yennawar for assistance with APS and laboratory X-ray diffraction respectively.

Funders	Funder number
DOE-NNSA	DE-NA0007
National Science Foundation
U.S. Department of Energy
Office of Science	DE-SC0001057
Argonne National Laboratory
Oak Ridge National Laboratory
National Science Foundation

Access to Document

10.1021/jacs.7b13247

Cite this

@article{fd4007116a6a4f179f484457c6d6208b,

title = "Carbon nitride nanothread crystals derived from pyridine",

abstract = "Carbon nanothreads are a new one-dimensional sp3 carbon nanomaterial. They assemble into hexagonal crystals in a room temperature, nontopochemical solid-state reaction induced by slow compression of benzene to 23 GPa. Here we show that pyridine also reacts under compression to form a well-ordered sp3 product: C5NH5 carbon nitride nanothreads. Solid pyridine has a different crystal structure from solid benzene, so the nontopochemical formation of low-dimensional crystalline solids by slow compression of small aromatics may be a general phenomenon that enables chemical design of properties. The nitrogen in the carbon nitride nanothreads may improve processability, alters photoluminescence, and is predicted to reduce the bandgap.",

author = "Xiang Li and Tao Wang and Pu Duan and Maria Baldini and Huang, {Haw Tyng} and Bo Chen and Juhl, {Stephen J.} and Daniel Koeplinger and Crespi, {Vincent H.} and Klaus Schmidt-Rohr and Roald Hoffmann and Nasim Alem and Malcolm Guthrie and Xin Zhang and Badding, {John V.}",

note = "Publisher Copyright: {\textcopyright} 2018 American Chemical Society.",

year = "2018",

month = apr,

day = "18",

doi = "10.1021/jacs.7b13247",

language = "English",

volume = "140",

pages = "4969--4972",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "15",

}

TY - JOUR

T1 - Carbon nitride nanothread crystals derived from pyridine

AU - Li, Xiang

AU - Wang, Tao

AU - Duan, Pu

AU - Baldini, Maria

AU - Huang, Haw Tyng

AU - Chen, Bo

AU - Juhl, Stephen J.

AU - Koeplinger, Daniel

AU - Crespi, Vincent H.

AU - Schmidt-Rohr, Klaus

AU - Hoffmann, Roald

AU - Alem, Nasim

AU - Guthrie, Malcolm

AU - Zhang, Xin

AU - Badding, John V.

PY - 2018/4/18

Y1 - 2018/4/18

N2 - Carbon nanothreads are a new one-dimensional sp3 carbon nanomaterial. They assemble into hexagonal crystals in a room temperature, nontopochemical solid-state reaction induced by slow compression of benzene to 23 GPa. Here we show that pyridine also reacts under compression to form a well-ordered sp3 product: C5NH5 carbon nitride nanothreads. Solid pyridine has a different crystal structure from solid benzene, so the nontopochemical formation of low-dimensional crystalline solids by slow compression of small aromatics may be a general phenomenon that enables chemical design of properties. The nitrogen in the carbon nitride nanothreads may improve processability, alters photoluminescence, and is predicted to reduce the bandgap.

AB - Carbon nanothreads are a new one-dimensional sp3 carbon nanomaterial. They assemble into hexagonal crystals in a room temperature, nontopochemical solid-state reaction induced by slow compression of benzene to 23 GPa. Here we show that pyridine also reacts under compression to form a well-ordered sp3 product: C5NH5 carbon nitride nanothreads. Solid pyridine has a different crystal structure from solid benzene, so the nontopochemical formation of low-dimensional crystalline solids by slow compression of small aromatics may be a general phenomenon that enables chemical design of properties. The nitrogen in the carbon nitride nanothreads may improve processability, alters photoluminescence, and is predicted to reduce the bandgap.

UR - http://www.scopus.com/inward/record.url?scp=85045661498&partnerID=8YFLogxK

U2 - 10.1021/jacs.7b13247

DO - 10.1021/jacs.7b13247

M3 - Article

C2 - 29569919

AN - SCOPUS:85045661498

SN - 0002-7863

VL - 140

SP - 4969

EP - 4972

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 15

ER -

Carbon nitride nanothread crystals derived from pyridine

Abstract

Funding

Access to Document

Other files and links

Fingerprint

Cite this