Bowl-in-bowl complex formation with mixed sized calixarenes: Adaptivity towards guest binding

Arnab Dawn; Andrew Eisenhart; Marzieh Mirzamani; Thomas L. Beck; Harshita Kumari

doi:10.1039/c8cc03415j

Bowl-in-bowl complex formation with mixed sized calixarenes: Adaptivity towards guest binding

Arnab Dawn, Andrew Eisenhart, Marzieh Mirzamani, Thomas L. Beck, Harshita Kumari

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

We demonstrated the organization of two differently sized calixarenes C-methylresorcin[4]arene (RsC1) and either calix[6]arene (Calix6) or calix[8]arene (Calix8), where the lower rim of RsC1 partially overlaps with the upper rim of Calix6 or Calix8. An adaptive nature of the heteromacrocyclic assembly towards the binding of a model guest has been observed.

Original language	English
Pages (from-to)	7131-7134
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	52
DOIs	https://doi.org/10.1039/c8cc03415j
State	Published - 2018
Externally published	Yes

Funding

The work was supported by the startup funds CoP, UC (H. K.). We acknowledge NSF grant CHE-1565632 for partial support (TLB). We also acknowledge an extensive grant of computer resources at the Ohio Supercomputer Center where the simulations were performed. We thank Dr Boualem Hammouda for the help in the SANS experiment set up at NIST.

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abstract = "We demonstrated the organization of two differently sized calixarenes C-methylresorcin[4]arene (RsC1) and either calix[6]arene (Calix6) or calix[8]arene (Calix8), where the lower rim of RsC1 partially overlaps with the upper rim of Calix6 or Calix8. An adaptive nature of the heteromacrocyclic assembly towards the binding of a model guest has been observed.",

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AU - Kumari, Harshita

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AB - We demonstrated the organization of two differently sized calixarenes C-methylresorcin[4]arene (RsC1) and either calix[6]arene (Calix6) or calix[8]arene (Calix8), where the lower rim of RsC1 partially overlaps with the upper rim of Calix6 or Calix8. An adaptive nature of the heteromacrocyclic assembly towards the binding of a model guest has been observed.

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Bowl-in-bowl complex formation with mixed sized calixarenes: Adaptivity towards guest binding

Abstract

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