Bis[bis(3-phenylpyrazol-1-yl)(pyrazol-1-yl)methane]copper(II) bis(perchlorate) acetonitrile disolvate

M. Scott Goodman; Margaret A. Goodman; Andrey Y. Kovalevsky; Alexander Y. Nazarenko; Donald Pope

doi:10.1107/S0108270105041661

Bis[bis(3-phenylpyrazol-1-yl)(pyrazol-1-yl)methane]copper(II) bis(perchlorate) acetonitrile disolvate

M. Scott Goodman
, Margaret A. Goodman
, Andrey Y. Kovalevsky
, Alexander Y. Nazarenko
, Donald Pope

Research output: Contribution to journal › Article › peer-review

Abstract

The title copper(II) complex, [Cu(C₂₂H₁₈N ₆)₂](ClO₄)₂·2C ₂H₃N, comprises two neutral substituted tris(pyrazol-1-yl)methane ligands bonded to a central Cu^II ion, which is positioned on a crystallographic inversion center. Six Cu - N bonds are arranged in a distorted octahedral fashion. The unsubstituted pyrazole rings on each ligand are oriented trans with respect to each other, interdigitated with the two 3-phenylpyrazole rings of the other ligand.

Original language	English
Pages (from-to)	m30-m32
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	62
Issue number	2
DOIs	https://doi.org/10.1107/S0108270105041661
State	Published - Feb 2006
Externally published	Yes

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title = "Bis[bis(3-phenylpyrazol-1-yl)(pyrazol-1-yl)methane]copper(II) bis(perchlorate) acetonitrile disolvate",

abstract = "The title copper(II) complex, [Cu(C22H18N 6)2](ClO4)2·2C 2H3N, comprises two neutral substituted tris(pyrazol-1-yl)methane ligands bonded to a central CuII ion, which is positioned on a crystallographic inversion center. Six Cu - N bonds are arranged in a distorted octahedral fashion. The unsubstituted pyrazole rings on each ligand are oriented trans with respect to each other, interdigitated with the two 3-phenylpyrazole rings of the other ligand.",

author = "Goodman, \{M. Scott\} and Goodman, \{Margaret A.\} and Kovalevsky, \{Andrey Y.\} and Nazarenko, \{Alexander Y.\} and Donald Pope",

year = "2006",

month = feb,

doi = "10.1107/S0108270105041661",

language = "English",

volume = "62",

pages = "m30--m32",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

number = "2",

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TY - JOUR

T1 - Bis[bis(3-phenylpyrazol-1-yl)(pyrazol-1-yl)methane]copper(II) bis(perchlorate) acetonitrile disolvate

AU - Goodman, M. Scott

AU - Goodman, Margaret A.

AU - Kovalevsky, Andrey Y.

AU - Nazarenko, Alexander Y.

AU - Pope, Donald

PY - 2006/2

Y1 - 2006/2

N2 - The title copper(II) complex, [Cu(C22H18N 6)2](ClO4)2·2C 2H3N, comprises two neutral substituted tris(pyrazol-1-yl)methane ligands bonded to a central CuII ion, which is positioned on a crystallographic inversion center. Six Cu - N bonds are arranged in a distorted octahedral fashion. The unsubstituted pyrazole rings on each ligand are oriented trans with respect to each other, interdigitated with the two 3-phenylpyrazole rings of the other ligand.

AB - The title copper(II) complex, [Cu(C22H18N 6)2](ClO4)2·2C 2H3N, comprises two neutral substituted tris(pyrazol-1-yl)methane ligands bonded to a central CuII ion, which is positioned on a crystallographic inversion center. Six Cu - N bonds are arranged in a distorted octahedral fashion. The unsubstituted pyrazole rings on each ligand are oriented trans with respect to each other, interdigitated with the two 3-phenylpyrazole rings of the other ligand.

UR - https://www.scopus.com/pages/publications/33645024087

U2 - 10.1107/S0108270105041661

DO - 10.1107/S0108270105041661

M3 - Article

AN - SCOPUS:33645024087

SN - 0108-2701

VL - 62

SP - m30-m32

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 2

ER -

Bis[bis(3-phenylpyrazol-1-yl)(pyrazol-1-yl)methane]copper(II) bis(perchlorate) acetonitrile disolvate

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