B(C6F5)3-catalyzed methylation of amines using CO2 as a C1 building block

Zhenzhen Yang; Bo Yu; Hongye Zhang; Yanfei Zhao; Guipeng Ji; Zhishuang Ma; Xiang Gao; Zhimin Liu

doi:10.1039/c5gc01386k

B(C₆F₅)₃-catalyzed methylation of amines using CO₂ as a C1 building block

Zhenzhen Yang, Bo Yu, Hongye Zhang, Yanfei Zhao, Guipeng Ji, Zhishuang Ma, Xiang Gao, Zhimin Liu

Research output: Contribution to journal › Article › peer-review

86 Scopus citations

Abstract

B(C₆F₅)₃ was proven to be an efficient metal-free catalyst for the methylation of amines using CO₂ as a C1 building block in the presence of hydrosilanes under easy-handling conditions. A broad range of N-alkylanilines, dialkylamines and primary anilines all proceeded well under the catalytic conditions.

Original language	English
Pages (from-to)	4189-4193
Number of pages	5
Journal	Green Chemistry
Volume	17
Issue number	8
DOIs	https://doi.org/10.1039/c5gc01386k
State	Published - Aug 1 2015
Externally published	Yes

Funding

Funders	Funder number
National Natural Science Foundation of China	21321063, 21402208, 21125314

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10.1039/c5gc01386k

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abstract = "B(C6F5)3 was proven to be an efficient metal-free catalyst for the methylation of amines using CO2 as a C1 building block in the presence of hydrosilanes under easy-handling conditions. A broad range of N-alkylanilines, dialkylamines and primary anilines all proceeded well under the catalytic conditions.",

author = "Zhenzhen Yang and Bo Yu and Hongye Zhang and Yanfei Zhao and Guipeng Ji and Zhishuang Ma and Xiang Gao and Zhimin Liu",

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AU - Yang, Zhenzhen

AU - Yu, Bo

AU - Zhang, Hongye

AU - Zhao, Yanfei

AU - Ji, Guipeng

AU - Ma, Zhishuang

AU - Gao, Xiang

AU - Liu, Zhimin

PY - 2015/8/1

Y1 - 2015/8/1

N2 - B(C6F5)3 was proven to be an efficient metal-free catalyst for the methylation of amines using CO2 as a C1 building block in the presence of hydrosilanes under easy-handling conditions. A broad range of N-alkylanilines, dialkylamines and primary anilines all proceeded well under the catalytic conditions.

AB - B(C6F5)3 was proven to be an efficient metal-free catalyst for the methylation of amines using CO2 as a C1 building block in the presence of hydrosilanes under easy-handling conditions. A broad range of N-alkylanilines, dialkylamines and primary anilines all proceeded well under the catalytic conditions.

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U2 - 10.1039/c5gc01386k

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M3 - Article

AN - SCOPUS:84938538044

SN - 1463-9262

VL - 17

SP - 4189

EP - 4193

JO - Green Chemistry

JF - Green Chemistry

IS - 8

ER -

B(C₆F₅)₃-catalyzed methylation of amines using CO₂ as a C1 building block

Abstract

Funding

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