Azo-functionalized microporous organic polymers: Synthesis and applications in CO2 capture and conversion

Zhenzhen Yang; Hongye Zhang; Bo Yu; Yanfei Zhao; Zhishuang Ma; Guipeng Ji; Buxing Han; Zhimin Liu

doi:10.1039/c5cc03151f

Azo-functionalized microporous organic polymers: Synthesis and applications in CO₂ capture and conversion

Zhenzhen Yang, Hongye Zhang, Bo Yu, Yanfei Zhao, Zhishuang Ma, Guipeng Ji, Buxing Han, Zhimin Liu

Research output: Contribution to journal › Article › peer-review

81 Scopus citations

Abstract

Azo-functionalized MOPs (Azo-MOPs) were synthesized via oxidative polymerization of aromatic amines catalyzed by t-BuOCl/NaI (25 °C, 1 h, yield: >95%), which displayed an excellent coordinating ability with a Ru complex. The resulting Ru-coordinated Azo-MOPs displayed high CO₂ capacity and high performances for catalyzing the methylation of amines with CO₂ under low pressure (0.5 MPa).

Original language	English
Pages (from-to)	11576-11579
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	58
DOIs	https://doi.org/10.1039/c5cc03151f
State	Published - Jul 25 2015
Externally published	Yes

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10.1039/c5cc03151f

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title = "Azo-functionalized microporous organic polymers: Synthesis and applications in CO2 capture and conversion",

abstract = "Azo-functionalized MOPs (Azo-MOPs) were synthesized via oxidative polymerization of aromatic amines catalyzed by t-BuOCl/NaI (25 °C, 1 h, yield: >95%), which displayed an excellent coordinating ability with a Ru complex. The resulting Ru-coordinated Azo-MOPs displayed high CO2 capacity and high performances for catalyzing the methylation of amines with CO2 under low pressure (0.5 MPa).",

author = "Zhenzhen Yang and Hongye Zhang and Bo Yu and Yanfei Zhao and Zhishuang Ma and Guipeng Ji and Buxing Han and Zhimin Liu",

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TY - JOUR

T1 - Azo-functionalized microporous organic polymers

T2 - Synthesis and applications in CO2 capture and conversion

AU - Yang, Zhenzhen

AU - Zhang, Hongye

AU - Yu, Bo

AU - Zhao, Yanfei

AU - Ma, Zhishuang

AU - Ji, Guipeng

AU - Han, Buxing

AU - Liu, Zhimin

PY - 2015/7/25

Y1 - 2015/7/25

N2 - Azo-functionalized MOPs (Azo-MOPs) were synthesized via oxidative polymerization of aromatic amines catalyzed by t-BuOCl/NaI (25 °C, 1 h, yield: >95%), which displayed an excellent coordinating ability with a Ru complex. The resulting Ru-coordinated Azo-MOPs displayed high CO2 capacity and high performances for catalyzing the methylation of amines with CO2 under low pressure (0.5 MPa).

AB - Azo-functionalized MOPs (Azo-MOPs) were synthesized via oxidative polymerization of aromatic amines catalyzed by t-BuOCl/NaI (25 °C, 1 h, yield: >95%), which displayed an excellent coordinating ability with a Ru complex. The resulting Ru-coordinated Azo-MOPs displayed high CO2 capacity and high performances for catalyzing the methylation of amines with CO2 under low pressure (0.5 MPa).

UR - http://www.scopus.com/inward/record.url?scp=84936109005&partnerID=8YFLogxK

U2 - 10.1039/c5cc03151f

DO - 10.1039/c5cc03151f

M3 - Article

AN - SCOPUS:84936109005

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VL - 51

SP - 11576

EP - 11579

JO - Chemical Communications

JF - Chemical Communications

IS - 58

ER -

Azo-functionalized microporous organic polymers: Synthesis and applications in CO₂ capture and conversion

Abstract

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