Au137(SR)56nanomolecules: Composition, optical spectroscopy, electrochemistry and electrocatalytic reduction of CO2

Vijay Reddy Jupally; Asantha C. Dharmaratne; David Crasto; Aron J. Huckaba; Chanaka Kumara; Praneeth Reddy Nimmala; Nuwan Kothalawala; Jared H. Delcamp; Amala Dass

doi:10.1039/c4cc03424d

Au₁₃₇(SR)₅₆nanomolecules: Composition, optical spectroscopy, electrochemistry and electrocatalytic reduction of CO₂

Vijay Reddy Jupally
, Asantha C. Dharmaratne
, David Crasto
, Aron J. Huckaba
, Chanaka Kumara
, Praneeth Reddy Nimmala
, Nuwan Kothalawala
, Jared H. Delcamp
, Amala Dass

Research output: Contribution to journal › Article › peer-review

57 Scopus citations

Abstract

Au₁₃₇(SR)₅₆, a nanomolecule with a precise number of metal atoms and ligands, was synthesized. The composition was confirmed by MALDI and ESI mass spectrometry using three unique ligands (–SCH₂CH₂Ph, –SC₆H₁₃, and –SC₄H₉) and nano-alloys with Ag and Pd. The electrocatalytic properties were tested for CO₂reduction.

Original language	English
Pages (from-to)	9895-9898
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	69
DOIs	https://doi.org/10.1039/c4cc03424d
State	Published - Jul 31 2014
Externally published	Yes

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10.1039/c4cc03424d

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abstract = "Au137(SR)56, a nanomolecule with a precise number of metal atoms and ligands, was synthesized. The composition was confirmed by MALDI and ESI mass spectrometry using three unique ligands (–SCH2CH2Ph, –SC6H13, and –SC4H9) and nano-alloys with Ag and Pd. The electrocatalytic properties were tested for CO2reduction.",

author = "Jupally, \{Vijay Reddy\} and Dharmaratne, \{Asantha C.\} and David Crasto and Huckaba, \{Aron J.\} and Chanaka Kumara and Nimmala, \{Praneeth Reddy\} and Nuwan Kothalawala and Delcamp, \{Jared H.\} and Amala Dass",

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doi = "10.1039/c4cc03424d",

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publisher = "Royal Society of Chemistry",

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T2 - Composition, optical spectroscopy, electrochemistry and electrocatalytic reduction of CO2

AU - Jupally, Vijay Reddy

AU - Dharmaratne, Asantha C.

AU - Crasto, David

AU - Huckaba, Aron J.

AU - Kumara, Chanaka

AU - Nimmala, Praneeth Reddy

AU - Kothalawala, Nuwan

AU - Delcamp, Jared H.

AU - Dass, Amala

PY - 2014/7/31

Y1 - 2014/7/31

N2 - Au137(SR)56, a nanomolecule with a precise number of metal atoms and ligands, was synthesized. The composition was confirmed by MALDI and ESI mass spectrometry using three unique ligands (–SCH2CH2Ph, –SC6H13, and –SC4H9) and nano-alloys with Ag and Pd. The electrocatalytic properties were tested for CO2reduction.

AB - Au137(SR)56, a nanomolecule with a precise number of metal atoms and ligands, was synthesized. The composition was confirmed by MALDI and ESI mass spectrometry using three unique ligands (–SCH2CH2Ph, –SC6H13, and –SC4H9) and nano-alloys with Ag and Pd. The electrocatalytic properties were tested for CO2reduction.

UR - https://www.scopus.com/pages/publications/84905460051

U2 - 10.1039/c4cc03424d

DO - 10.1039/c4cc03424d

M3 - Article

AN - SCOPUS:84905460051

SN - 1359-7345

VL - 50

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JO - Chemical Communications

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ER -

Au₁₃₇(SR)₅₆nanomolecules: Composition, optical spectroscopy, electrochemistry and electrocatalytic reduction of CO₂

Abstract

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