Atomistic investigation of calcium sulfonate and lithium complex grease tribofilms under severe sliding conditions

Vikram Bedekar, Kuldeep Mistry, Rohit Voothaluru, Jun Qu, Jonathan Poplawsky

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

Innovative grease chemistries and additives are continuously developed to meet challenging applications such as wind energy bearings and offshore/underwater applications. The non-equilibrium and transient structures within interfacial tribofilms play an influential role in the service life of a component. Atom probe tomography and transmission electron microscopy studies were performed to investigate the tribofilms formed by lithium complex and calcium sulfonate grease thickeners. The study reveals that morphology, amorphicity, nanostructure, and atomic layering play an influential role in the exceptional wear and corrosion performance of calcium sulfonate thickeners.

Original languageEnglish
Pages (from-to)497-500
Number of pages4
JournalCIRP Annals - Manufacturing Technology
Volume71
Issue number1
DOIs
StatePublished - Jan 2022

Funding

The authors thank The Timken Company for supporting the work and providing the permission to publish. The authors thank Mr. Bob Pendergrass (The Timken Company) and Mr. Henk Colijn (OSU) for TEM sample preparation and TEM analysis, respectively. The authors would also like to thank James Burns (ORNL) for his assistance in performing APT sample preparation and running the APT experiments. APT was conducted at ORNL's Center for Nanophase Materials Sciences (CNMS), which is a U.S. DOE Office of Science User Facility.

Keywords

  • Lubrication
  • Severe plastic deformation
  • Tribofilm

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