Argon adsorption on Cu3(benzene-1,3,5-tricarboxylate) 2(H2O)3 metal-organic framework

V. Krungleviciute; K. Lask; L. Heroux; A. D. Migone; J. Y. Lee; J. Li; A. Skoulidas

doi:10.1021/la061871a

Argon adsorption on Cu₃(benzene-1,3,5-tricarboxylate) ₂(H₂O)₃ metal-organic framework

V. Krungleviciute, K. Lask, L. Heroux, A. D. Migone, J. Y. Lee, J. Li, A. Skoulidas

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Abstract

Using volumetric adsorption techniques, we have measured the adsorption of argon on Cu₃(BTC)₂(H₂O)₃, (BTC = benzene-1,3,5-tricarboxylate), a microporous metal-organic framework structure, at temperatures between 66 and 143 K. In addition to the experiments, we have used Grand Canonical Monte Carlo simulations to calculate the adsorption isotherm of argon at 87 K. Our experimental and theoretical results are compared to those of previous studies. The experiments were performed using a high density of points, allowing us to obtain, in detail, the isosteric heat's coverage dependence. Our values from the simulations are in reasonable agreement with those obtained in the experiments.

Original language	English
Pages (from-to)	3106-3109
Number of pages	4
Journal	Langmuir
Volume	23
Issue number	6
DOIs	https://doi.org/10.1021/la061871a
State	Published - Mar 13 2007

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abstract = "Using volumetric adsorption techniques, we have measured the adsorption of argon on Cu3(BTC)2(H2O)3, (BTC = benzene-1,3,5-tricarboxylate), a microporous metal-organic framework structure, at temperatures between 66 and 143 K. In addition to the experiments, we have used Grand Canonical Monte Carlo simulations to calculate the adsorption isotherm of argon at 87 K. Our experimental and theoretical results are compared to those of previous studies. The experiments were performed using a high density of points, allowing us to obtain, in detail, the isosteric heat's coverage dependence. Our values from the simulations are in reasonable agreement with those obtained in the experiments.",

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T1 - Argon adsorption on Cu3(benzene-1,3,5-tricarboxylate) 2(H2O)3 metal-organic framework

AU - Krungleviciute, V.

AU - Lask, K.

AU - Heroux, L.

AU - Migone, A. D.

AU - Lee, J. Y.

AU - Li, J.

AU - Skoulidas, A.

PY - 2007/3/13

Y1 - 2007/3/13

N2 - Using volumetric adsorption techniques, we have measured the adsorption of argon on Cu3(BTC)2(H2O)3, (BTC = benzene-1,3,5-tricarboxylate), a microporous metal-organic framework structure, at temperatures between 66 and 143 K. In addition to the experiments, we have used Grand Canonical Monte Carlo simulations to calculate the adsorption isotherm of argon at 87 K. Our experimental and theoretical results are compared to those of previous studies. The experiments were performed using a high density of points, allowing us to obtain, in detail, the isosteric heat's coverage dependence. Our values from the simulations are in reasonable agreement with those obtained in the experiments.

AB - Using volumetric adsorption techniques, we have measured the adsorption of argon on Cu3(BTC)2(H2O)3, (BTC = benzene-1,3,5-tricarboxylate), a microporous metal-organic framework structure, at temperatures between 66 and 143 K. In addition to the experiments, we have used Grand Canonical Monte Carlo simulations to calculate the adsorption isotherm of argon at 87 K. Our experimental and theoretical results are compared to those of previous studies. The experiments were performed using a high density of points, allowing us to obtain, in detail, the isosteric heat's coverage dependence. Our values from the simulations are in reasonable agreement with those obtained in the experiments.

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Argon adsorption on Cu₃(benzene-1,3,5-tricarboxylate) ₂(H₂O)₃ metal-organic framework

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