Application of199Hg solid-state NMR to Hg based HTSC

W. Hoffmann, H. Breitzke, M. Baenitz, M. Heinze, K. Lüders, G. Buntkowsky, H. H. Limbach, E. V. Antipov, A. A. Gippius, O. Loebich, H. R. Khan, M. Paranthaman, J. R. Thompson

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5 Scopus citations

Abstract

It is proposed to study Hg-oxide ceramics, which are high-temperature superconductors, with 199Hg NMR spectroscopy. As an exemplary application of this method first room-temperature 199Hg spectra and spin-lattice relaxation times of samples with different macrostructure are presented. A spin-lattice relaxation time of T1=35 ms is found. All samples exhibit similar characteristic powder spectra caused by an axially symmetric 199Hg spin interaction. The isotropic value and the anisotropy of the tensor relative to solid HgCl2 as a standard substance is estimated.

Original languageEnglish
Pages (from-to)225-229
Number of pages5
JournalPhysica C: Superconductivity and its Applications
Volume227
Issue number3-4
DOIs
StatePublished - Jul 1 1994

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