Abstract
We present in situ x-ray scattering measurements of the surface structures of [Formula presented] (001) in equilibrium with PbO vapor. At 875 to 1025 K, a reconstruction having [Formula presented] symmetry is present under most conditions, while a [Formula presented] reconstruction occurs under PbO-poor conditions. The atomic structure of the [Formula presented] phase is found to consist of a single layer of an antiferrodistortive structure with oxygen cages counter-rotated by 10° about the titanium ions.
Original language | English |
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Pages (from-to) | 4 |
Number of pages | 1 |
Journal | Physical Review Letters |
Volume | 88 |
Issue number | 1 |
DOIs | |
State | Published - 2002 |
Externally published | Yes |