Annealing temperature dependence of TiB 2 Schottky barrier contacts on n-GaN

Rohit Khanna, S. J. Pearton, F. Ren, I. Kravchenko

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

The annealing temperature (25-700°C) dependence of Schottky contact characteristics on n-GaN using a TiB 2/Ti/Au metallization scheme deposited by sputtering is reported. The Schottky barrier height increased from 0.65 to 0.68 eV as the anneal temperature was varied from 25°C to 350°C and decreased to 0.55 eV after annealing at 700°C. The barrier height showed no measurable dependence on measurement temperature up to 150°C. The elemental profile obtained from samples annealed at 350°C showed limited Ti diffusion from the elemental Ti layer into the gold layer. Annealing at 700°C produced significant out-diffusion of this layer, while the TiB 2 layer retained its stability. These contacts show promise for applications requiring good thermal stability, such as power amplifiers, but much more work is needed to establish their long-term reliability. In addition, TiB 2 has a strong propensity for oxidation, and it is imperative that overlayers such as Au be deposited in the same deposition chamber.

Original languageEnglish
Pages (from-to)658-662
Number of pages5
JournalJournal of Electronic Materials
Volume35
Issue number4
DOIs
StatePublished - Apr 2006
Externally publishedYes

Funding

The work at UF is partially supported by the AFOSR (F49620-03-1-0370), the Army Research Office (DAAD19-01-1-0603), and the NSF (CTS-0301178, monitored by Dr. M. Burka and Dr. D. Senich, and DMR 0400416, Dr. L. Hess).

FundersFunder number
National Science FoundationCTS-0301178, DMR 0400416
Air Force Office of Scientific ResearchF49620-03-1-0370
Army Research OfficeDAAD19-01-1-0603
University of Florida

    Keywords

    • GaN
    • Schottky barrier height
    • Thermal stability

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