Anion encapsulation and dynamics in self-assembled coordination cages

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219 Scopus citations

Abstract

The ability of cationic coordination cages to act as anion receptors is reviewed, with an emphasis on the anion encapsulation chemistry and the dynamics of cage assembly, anion exchange, and other anion-induced structural transformations. The first part of the review describes various examples of anion-encapsulating coordination cages, categorized on the basis of their M xLy stoichiometry (M = metal cation; L = organic ligand). The second part deals with the dynamic aspects of anion encapsulation, including the kinetics and mechanism of anion binding, release, and exchange, as well as the structural evolution of the coordination complexes involved.

Original languageEnglish
Pages (from-to)1813-1824
Number of pages12
JournalChemical Society Reviews
Volume43
Issue number6
DOIs
StatePublished - Mar 21 2014

Funding

FundersFunder number
U.S. Department of Energy

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