Anion-π interactions in crystal structures: Commonplace or extraordinary?

Benjamin P. Hay; Radu Custelcean

doi:10.1021/cg900308b

Anion-π interactions in crystal structures: Commonplace or extraordinary?

Benjamin P. Hay, Radu Custelcean

Chemical Separations Group

Research output: Contribution to journal › Review article › peer-review

119 Scopus citations

Abstract

An in-depth analysis of the distribution of anions about planar six-membered rings in the Cambridge Structural Database reveals anion-π interactions with charge-neutral π systems to be extremely rare in crystal structures. The predominant interaction motif is C-H · · · anion hydrogen bonding.

Original language	English
Pages (from-to)	2539-2545
Number of pages	7
Journal	Crystal Growth and Design
Volume	9
Issue number	6
DOIs	https://doi.org/10.1021/cg900308b
State	Published - Jun 3 2009

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title = "Anion-π interactions in crystal structures: Commonplace or extraordinary?",

abstract = "An in-depth analysis of the distribution of anions about planar six-membered rings in the Cambridge Structural Database reveals anion-π interactions with charge-neutral π systems to be extremely rare in crystal structures. The predominant interaction motif is C-H · · · anion hydrogen bonding.",

author = "Hay, \{Benjamin P.\} and Radu Custelcean",

year = "2009",

month = jun,

day = "3",

doi = "10.1021/cg900308b",

language = "English",

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journal = "Crystal Growth and Design",

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T1 - Anion-π interactions in crystal structures

T2 - Commonplace or extraordinary?

AU - Hay, Benjamin P.

AU - Custelcean, Radu

PY - 2009/6/3

Y1 - 2009/6/3

N2 - An in-depth analysis of the distribution of anions about planar six-membered rings in the Cambridge Structural Database reveals anion-π interactions with charge-neutral π systems to be extremely rare in crystal structures. The predominant interaction motif is C-H · · · anion hydrogen bonding.

AB - An in-depth analysis of the distribution of anions about planar six-membered rings in the Cambridge Structural Database reveals anion-π interactions with charge-neutral π systems to be extremely rare in crystal structures. The predominant interaction motif is C-H · · · anion hydrogen bonding.

UR - https://www.scopus.com/pages/publications/66849138180

U2 - 10.1021/cg900308b

DO - 10.1021/cg900308b

M3 - Review article

AN - SCOPUS:66849138180

SN - 1528-7483

VL - 9

SP - 2539

EP - 2545

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 6

ER -

Anion-π interactions in crystal structures: Commonplace or extraordinary?

Abstract

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