"Anhydrolycaconitine," a new diterpene alkaloid from aconitum septentrionale K

M. S. Yunusov; E. M. Tsyrlina; E. D. Khairitdinova; L. V. Spirikhin; A. Yu Kovalevsky; M. Yu Antipin

doi:10.1007/BF02495171

"Anhydrolycaconitine," a new diterpene alkaloid from aconitum septentrionale K

M. S. Yunusov, E. M. Tsyrlina, E. D. Khairitdinova, L. V. Spirikhin, A. Yu Kovalevsky, M. Yu Antipin

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

A new alkaloid, anhydrolycaconitine (C₃₆H₄₆N₂O₉), was isolated from roots of of Aconitum septentrionale K. Based on the results of ¹H and ¹³C NMR and IR spectroscopy and mass spectrometry of the alkaloid and the product of its alkaline hydrolysis and on the data of X-ray diffraction analysis of the hydrolysis product, the structure of 1α,6β,14α,16β-tetramethoxy-7-oxo-18-succinylanthranoyloxy- 17-(7→8)abeo-aconane was assigned to anhydrolycaconitine.

Original language	English
Pages (from-to)	1629-1633
Number of pages	5
Journal	Russian Chemical Bulletin
Volume	49
Issue number	9
DOIs	https://doi.org/10.1007/BF02495171
State	Published - Sep 2000
Externally published	Yes

Funding

This work was financially supported by the Russian Foundation for Basic Research (Project No. 99-03-33509).

Keywords

Diterpene alkaloids
Northern wolfsbane Aconitum septentrionale K., roots

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10.1007/BF02495171

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title = "{"}Anhydrolycaconitine,{"} a new diterpene alkaloid from aconitum septentrionale K",

abstract = "A new alkaloid, anhydrolycaconitine (C36H46N2O9), was isolated from roots of of Aconitum septentrionale K. Based on the results of 1H and 13C NMR and IR spectroscopy and mass spectrometry of the alkaloid and the product of its alkaline hydrolysis and on the data of X-ray diffraction analysis of the hydrolysis product, the structure of 1α,6β,14α,16β-tetramethoxy-7-oxo-18-succinylanthranoyloxy- 17-(7→8)abeo-aconane was assigned to anhydrolycaconitine.",

keywords = "Diterpene alkaloids, Northern wolfsbane Aconitum septentrionale K., roots",

author = "Yunusov, \{M. S.\} and Tsyrlina, \{E. M.\} and Khairitdinova, \{E. D.\} and Spirikhin, \{L. V.\} and Kovalevsky, \{A. Yu\} and Antipin, \{M. Yu\}",

year = "2000",

month = sep,

doi = "10.1007/BF02495171",

language = "English",

volume = "49",

pages = "1629--1633",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer",

number = "9",

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TY - JOUR

T1 - "Anhydrolycaconitine," a new diterpene alkaloid from aconitum septentrionale K

AU - Yunusov, M. S.

AU - Tsyrlina, E. M.

AU - Khairitdinova, E. D.

AU - Spirikhin, L. V.

AU - Kovalevsky, A. Yu

AU - Antipin, M. Yu

PY - 2000/9

Y1 - 2000/9

N2 - A new alkaloid, anhydrolycaconitine (C36H46N2O9), was isolated from roots of of Aconitum septentrionale K. Based on the results of 1H and 13C NMR and IR spectroscopy and mass spectrometry of the alkaloid and the product of its alkaline hydrolysis and on the data of X-ray diffraction analysis of the hydrolysis product, the structure of 1α,6β,14α,16β-tetramethoxy-7-oxo-18-succinylanthranoyloxy- 17-(7→8)abeo-aconane was assigned to anhydrolycaconitine.

AB - A new alkaloid, anhydrolycaconitine (C36H46N2O9), was isolated from roots of of Aconitum septentrionale K. Based on the results of 1H and 13C NMR and IR spectroscopy and mass spectrometry of the alkaloid and the product of its alkaline hydrolysis and on the data of X-ray diffraction analysis of the hydrolysis product, the structure of 1α,6β,14α,16β-tetramethoxy-7-oxo-18-succinylanthranoyloxy- 17-(7→8)abeo-aconane was assigned to anhydrolycaconitine.

KW - Diterpene alkaloids

KW - Northern wolfsbane Aconitum septentrionale K., roots

UR - https://www.scopus.com/pages/publications/0034337336

U2 - 10.1007/BF02495171

DO - 10.1007/BF02495171

M3 - Article

AN - SCOPUS:0034337336

SN - 1066-5285

VL - 49

SP - 1629

EP - 1633

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

IS - 9

ER -

"Anhydrolycaconitine," a new diterpene alkaloid from aconitum septentrionale K

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