Analysis of the relationship between stress-strain curve and filler aggregate structure by time-resolved two-dimensional Ultra-Small-Angle X-ray Scattering

Yuya Shinohara, Yoshiyuki Amemiya, Hiroyuki Kishimoto, Kiyoshige Muraoka, Tetsuo Mizoguchi, Yoshio Suzuki, Akihisa Takeuchi, Kentaro Uesugi, Naoto Yagi

Research output: Contribution to conferencePaperpeer-review

Abstract

Rubbers can be reinforced by filler such as carbon black and silica. The precise mechanism of reinforcement is, however, not well understood. In the present study, we have performed time-resolved two-dimensional Ultra Small-Angle X-ray Scattering (2D-USAXS) measurements of rubber filled with spherical silica particles as a model sample. The measured 2D-USAXS images under elongation showed anisotropic scattering patterns which originate from the anisotropic structure of silica aggregates. It has been clearly shown that the 2D-USAXS images shows corresponding hysteresis to that of stress-strain curve.

Original languageEnglish
Pages3227-3228
Number of pages2
StatePublished - 2005
Externally publishedYes
Event54th SPSJ Symposium on Macromolecules - Yamagata, Japan
Duration: Sep 20 2005Sep 22 2005

Conference

Conference54th SPSJ Symposium on Macromolecules
Country/TerritoryJapan
CityYamagata
Period09/20/0509/22/05

Keywords

  • 2D-USAXS
  • Filler
  • Rubber

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