An organophosphine oxide redox shuttle additive that delivers long-term overcharge protection for 4 v lithium-ion batteries

Jinhua Huang; Nasim Azimi; Lei Cheng; Ilya A. Shkrob; Zheng Xue; Junjie Zhang; Nancy L. Dietz Rago; Larry A. Curtiss; Khalil Amine; Zhengcheng Zhang; Lu Zhang

doi:10.1039/c5ta01326g

An organophosphine oxide redox shuttle additive that delivers long-term overcharge protection for 4 v lithium-ion batteries

Jinhua Huang, Nasim Azimi, Lei Cheng, Ilya A. Shkrob, Zheng Xue, Junjie Zhang, Nancy L. Dietz Rago, Larry A. Curtiss, Khalil Amine, Zhengcheng Zhang, Lu Zhang

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

Redox shuttle additives are used to protect Li-ion batteries from overcharge. Increased operating voltage requires striking a balance between a high redox potential and electrochemical stability. 1,4-Bis[bis(1-methylethyl)phosphinyl]-2,5-dimethoxybenzene (BPDB) exhibits a redox potential of 4.5 V vs. Li/Li⁺ and provides stable overcharge protection for 4 V cells delivering 95 cycles of 100% overcharge ratio.

Original language	English
Pages (from-to)	10710-10714
Number of pages	5
Journal	Journal of Materials Chemistry A
Volume	3
Issue number	20
DOIs	https://doi.org/10.1039/c5ta01326g
State	Published - May 28 2015
Externally published	Yes

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10.1039/c5ta01326g

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@article{a82123addbb24cd9b0374afe5d7e0340,

title = "An organophosphine oxide redox shuttle additive that delivers long-term overcharge protection for 4 v lithium-ion batteries",

abstract = "Redox shuttle additives are used to protect Li-ion batteries from overcharge. Increased operating voltage requires striking a balance between a high redox potential and electrochemical stability. 1,4-Bis[bis(1-methylethyl)phosphinyl]-2,5-dimethoxybenzene (BPDB) exhibits a redox potential of 4.5 V vs. Li/Li+ and provides stable overcharge protection for 4 V cells delivering 95 cycles of 100% overcharge ratio.",

author = "Jinhua Huang and Nasim Azimi and Lei Cheng and Shkrob, {Ilya A.} and Zheng Xue and Junjie Zhang and {Dietz Rago}, {Nancy L.} and Curtiss, {Larry A.} and Khalil Amine and Zhengcheng Zhang and Lu Zhang",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry. {\textcopyright} The Royal Society of Chemistry 2015.",

year = "2015",

month = may,

day = "28",

doi = "10.1039/c5ta01326g",

language = "English",

volume = "3",

pages = "10710--10714",

journal = "Journal of Materials Chemistry A",

issn = "2050-7488",

publisher = "Royal Society of Chemistry",

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}

TY - JOUR

T1 - An organophosphine oxide redox shuttle additive that delivers long-term overcharge protection for 4 v lithium-ion batteries

AU - Huang, Jinhua

AU - Azimi, Nasim

AU - Cheng, Lei

AU - Shkrob, Ilya A.

AU - Xue, Zheng

AU - Zhang, Junjie

AU - Dietz Rago, Nancy L.

AU - Curtiss, Larry A.

AU - Amine, Khalil

AU - Zhang, Zhengcheng

AU - Zhang, Lu

PY - 2015/5/28

Y1 - 2015/5/28

N2 - Redox shuttle additives are used to protect Li-ion batteries from overcharge. Increased operating voltage requires striking a balance between a high redox potential and electrochemical stability. 1,4-Bis[bis(1-methylethyl)phosphinyl]-2,5-dimethoxybenzene (BPDB) exhibits a redox potential of 4.5 V vs. Li/Li+ and provides stable overcharge protection for 4 V cells delivering 95 cycles of 100% overcharge ratio.

AB - Redox shuttle additives are used to protect Li-ion batteries from overcharge. Increased operating voltage requires striking a balance between a high redox potential and electrochemical stability. 1,4-Bis[bis(1-methylethyl)phosphinyl]-2,5-dimethoxybenzene (BPDB) exhibits a redox potential of 4.5 V vs. Li/Li+ and provides stable overcharge protection for 4 V cells delivering 95 cycles of 100% overcharge ratio.

UR - http://www.scopus.com/inward/record.url?scp=84929177426&partnerID=8YFLogxK

U2 - 10.1039/c5ta01326g

DO - 10.1039/c5ta01326g

M3 - Article

AN - SCOPUS:84929177426

SN - 2050-7488

VL - 3

SP - 10710

EP - 10714

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 20

ER -

An organophosphine oxide redox shuttle additive that delivers long-term overcharge protection for 4 v lithium-ion batteries

Abstract

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