An E.S.R. Study of Radical Cation Cyclization in the Radiolytic Oxidation of But-3-en-1-ol Solutions in Freon Matrices

Sheng Dai; Jih Tzong Wang; Ffrançon Williams

doi:10.1039/P19890001063

An E.S.R. Study of Radical Cation Cyclization in the Radiolytic Oxidation of But-3-en-1-ol Solutions in Freon Matrices

Sheng Dai
, Jih Tzong Wang
, Ffrançon Williams

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The radiolytic oxidation of but-3-en-1-ol in halogenoethane matrices produces e.s.r. signals from both the protonated tetrahydrofuran-3-yl radical and the allyl radical; the former species is readily attributable to the nucleophilic endo cyclization of radical cations generated from unassociated solute molecules whilst the allyl radical is thought to originate from the fragmentation of the alkoxyl radical produced from radical cations generated within solute clusters.

Original language	English
Pages (from-to)	1063-1064
Number of pages	2
Journal	Journal of the Chemical Society, Perkin Transactions 1
Issue number	5
DOIs	https://doi.org/10.1039/P19890001063
State	Published - 1989
Externally published	Yes

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10.1039/P19890001063

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title = "An E.S.R. Study of Radical Cation Cyclization in the Radiolytic Oxidation of But-3-en-1-ol Solutions in Freon Matrices",

abstract = "The radiolytic oxidation of but-3-en-1-ol in halogenoethane matrices produces e.s.r. signals from both the protonated tetrahydrofuran-3-yl radical and the allyl radical; the former species is readily attributable to the nucleophilic endo cyclization of radical cations generated from unassociated solute molecules whilst the allyl radical is thought to originate from the fragmentation of the alkoxyl radical produced from radical cations generated within solute clusters.",

author = "Sheng Dai and Wang, \{Jih Tzong\} and Ffran{\c c}on Williams",

year = "1989",

doi = "10.1039/P19890001063",

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pages = "1063--1064",

journal = "Journal of the Chemical Society, Perkin Transactions 1",

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AU - Dai, Sheng

AU - Wang, Jih Tzong

AU - Williams, Ffrançon

PY - 1989

Y1 - 1989

N2 - The radiolytic oxidation of but-3-en-1-ol in halogenoethane matrices produces e.s.r. signals from both the protonated tetrahydrofuran-3-yl radical and the allyl radical; the former species is readily attributable to the nucleophilic endo cyclization of radical cations generated from unassociated solute molecules whilst the allyl radical is thought to originate from the fragmentation of the alkoxyl radical produced from radical cations generated within solute clusters.

AB - The radiolytic oxidation of but-3-en-1-ol in halogenoethane matrices produces e.s.r. signals from both the protonated tetrahydrofuran-3-yl radical and the allyl radical; the former species is readily attributable to the nucleophilic endo cyclization of radical cations generated from unassociated solute molecules whilst the allyl radical is thought to originate from the fragmentation of the alkoxyl radical produced from radical cations generated within solute clusters.

UR - https://www.scopus.com/pages/publications/37049081820

U2 - 10.1039/P19890001063

DO - 10.1039/P19890001063

M3 - Article

AN - SCOPUS:37049081820

SN - 1470-4358

SP - 1063

EP - 1064

JO - Journal of the Chemical Society, Perkin Transactions 1

JF - Journal of the Chemical Society, Perkin Transactions 1

IS - 5

ER -

An E.S.R. Study of Radical Cation Cyclization in the Radiolytic Oxidation of But-3-en-1-ol Solutions in Freon Matrices

Abstract

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