TY - JOUR
T1 - An Energy-Dense, Powerful, Robust Bipolar Zinc–Ferrocene Redox-Flow Battery
AU - Luo, Jian
AU - Hu, Bo
AU - Hu, Maowei
AU - Wu, Wenda
AU - Liu, T. Leo
N1 - Publisher Copyright:
© 2022 Wiley-VCH GmbH.
PY - 2022/7/25
Y1 - 2022/7/25
N2 - Zinc metal represents a low-cost, high-capacity anode material to develop energy-dense aqueous redox-flow batteries (RFB). However, the energy-storage applications of traditional inorganic Zn halide flow batteries are primarily plagued by the material challenges of traditional halide cathode electrolytes (e.g., bromine), including corrosion, toxicity, and severe crossover. Herein, we report a bipolar zinc–ferrocene salt compound, zinc 1,1′-bis(3-sulfonatopropyl)ferrocene, Zn[Fc(SPr)2] (1.80 M solubility or 48.2 Ah L− charge storage capacity)—a robust, energy-dense, bipolar redox-active electrolyte material for RFBs. Zn[Fc(SPr)2]-based redox-flow batteries operated at high current densities of up to 200 mA cm−2 and delivered an energy efficiency of up to 81.5 % and a power density of up to 270.5 mW cm−2. A Zn[Fc(SPr)2] flow battery demonstrated an energy density of 20.2 Wh L−1 and displayed nearly 100 % capacity retention for 2000 cycles (1284 h or 53.5 days).
AB - Zinc metal represents a low-cost, high-capacity anode material to develop energy-dense aqueous redox-flow batteries (RFB). However, the energy-storage applications of traditional inorganic Zn halide flow batteries are primarily plagued by the material challenges of traditional halide cathode electrolytes (e.g., bromine), including corrosion, toxicity, and severe crossover. Herein, we report a bipolar zinc–ferrocene salt compound, zinc 1,1′-bis(3-sulfonatopropyl)ferrocene, Zn[Fc(SPr)2] (1.80 M solubility or 48.2 Ah L− charge storage capacity)—a robust, energy-dense, bipolar redox-active electrolyte material for RFBs. Zn[Fc(SPr)2]-based redox-flow batteries operated at high current densities of up to 200 mA cm−2 and delivered an energy efficiency of up to 81.5 % and a power density of up to 270.5 mW cm−2. A Zn[Fc(SPr)2] flow battery demonstrated an energy density of 20.2 Wh L−1 and displayed nearly 100 % capacity retention for 2000 cycles (1284 h or 53.5 days).
KW - Energy Storage
KW - Ferrocene
KW - Redox-Flow Batteries
KW - Zinc Batteries
UR - http://www.scopus.com/inward/record.url?scp=85131563142&partnerID=8YFLogxK
U2 - 10.1002/anie.202204030
DO - 10.1002/anie.202204030
M3 - Article
C2 - 35523722
AN - SCOPUS:85131563142
SN - 1433-7851
VL - 61
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 30
M1 - e202204030
ER -