An efficient and reusable “hairy” particle acid catalyst for the synthesis of 5-hydroxymethylfurfural from dehydration of fructose in water

Chengcheng Tian; Chunhui Bao; Andrew Binder; Zhenqian Zhu; Bin Hu; Yanglong Guo; Bin Zhao; Sheng Dai

doi:10.1039/c3cc43127d

An efficient and reusable “hairy” particle acid catalyst for the synthesis of 5-hydroxymethylfurfural from dehydration of fructose in water

Chengcheng Tian, Chunhui Bao, Andrew Binder, Zhenqian Zhu, Bin Hu, Yanglong Guo, Bin Zhao, Sheng Dai

Research output: Contribution to journal › Article › peer-review

41 Scopus citations

Abstract

Poly(4-styrenesulfonic acid) brush-grafted silica particles, synthesized by surface-initiated atom transfer radical polymerization, were employed as a reusable acid catalyst for dehydration of fructose to 5-hydroxymethylfurfural (HMF) in water. The particles exhibited a high activity with the HMF yield of up to 31%, in contrast to 26% from the corresponding free homopolymer catalyst.

Original language	English
Pages (from-to)	8668-8670
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	77
DOIs	https://doi.org/10.1039/c3cc43127d
State	Published - Aug 29 2013
Externally published	Yes

Funding

Funders	Funder number
National Science Foundation	1007986
National Science Foundation

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abstract = "Poly(4-styrenesulfonic acid) brush-grafted silica particles, synthesized by surface-initiated atom transfer radical polymerization, were employed as a reusable acid catalyst for dehydration of fructose to 5-hydroxymethylfurfural (HMF) in water. The particles exhibited a high activity with the HMF yield of up to 31%, in contrast to 26% from the corresponding free homopolymer catalyst.",

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AU - Tian, Chengcheng

AU - Bao, Chunhui

AU - Binder, Andrew

AU - Zhu, Zhenqian

AU - Hu, Bin

AU - Guo, Yanglong

AU - Zhao, Bin

AU - Dai, Sheng

PY - 2013/8/29

Y1 - 2013/8/29

N2 - Poly(4-styrenesulfonic acid) brush-grafted silica particles, synthesized by surface-initiated atom transfer radical polymerization, were employed as a reusable acid catalyst for dehydration of fructose to 5-hydroxymethylfurfural (HMF) in water. The particles exhibited a high activity with the HMF yield of up to 31%, in contrast to 26% from the corresponding free homopolymer catalyst.

AB - Poly(4-styrenesulfonic acid) brush-grafted silica particles, synthesized by surface-initiated atom transfer radical polymerization, were employed as a reusable acid catalyst for dehydration of fructose to 5-hydroxymethylfurfural (HMF) in water. The particles exhibited a high activity with the HMF yield of up to 31%, in contrast to 26% from the corresponding free homopolymer catalyst.

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U2 - 10.1039/c3cc43127d

DO - 10.1039/c3cc43127d

M3 - Article

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AN - SCOPUS:84883311942

SN - 1359-7345

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JO - Chemical Communications

JF - Chemical Communications

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ER -

An efficient and reusable “hairy” particle acid catalyst for the synthesis of 5-hydroxymethylfurfural from dehydration of fructose in water

Abstract

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