ALLOY DESIGN AND DEVELOPMENT OF HIGH CR CONTAINING FECRAL FERRITIC ALLOYS FOR EXTREME ENVIRONMENTS

Yukinori Yamamoto; Bruce A. Pint; Michael P. Brady; Sudarsanam Babu; Chih Hsiang Kuo; Benjamin Shassere

doi:10.31339/asm.cp.am-epri-2019p0628

ALLOY DESIGN AND DEVELOPMENT OF HIGH CR CONTAINING FECRAL FERRITIC ALLOYS FOR EXTREME ENVIRONMENTS

Yukinori Yamamoto
, Bruce A. Pint
, Michael P. Brady
, Sudarsanam Babu
, Chih Hsiang Kuo
, Benjamin Shassere

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

2 Scopus citations

Abstract

A new alloy design concept for creep- and corrosion-resistant, fully ferritic alloys was proposed for high-temperature structural applications in current/future fossil-fired power plants. The alloys, based on the Fe-30Cr-3Al (in weight percent) system with minor alloying additions of Nb, W, Si, Zr and/or Y, were designed for corrosion resistance though high Cr content, steam oxidation resistance through alumina-scale formation, and high-temperature creep performance through fine particle dispersion of Fe₂(Nb,W)-type Laves phase in the BCC-Fe matrix. Theses alloys are targeted for use in harsh environments such as combustion and/or steam containing atmospheres at 700°C or greater. The alloys, consisting of Fe-30Cr-3Al-1Nb-6W with minor alloying additions, exhibited a successful combination of oxidation, corrosion, and creep resistances comparable or superior to those of commercially available heat resistant austenitic stainless steels. An optimized thermo-mechanical treatment combined with selected minor alloying additions resulted in a refined grain structure with high thermal stability even at 1200°C, which improved room-temperature ductility without sacrificing the creep performance. The mechanism of grain refinement in the alloy system is discussed.

Original language	English
Title of host publication	Joint EPRI-123HiMAT International Conference on Advances in High-Temperature Materials - Proceedings from EPRI's 9th International Conference on Advances in Materials Technology for Fossil Power Plants and the 2nd International 123HiMAT Conference on High-Temperature Materials
Editors	John Shingledecker, Masao Takeyama
Publisher	ASM International
Pages	628-639
Number of pages	12
ISBN (Electronic)	9781627082716
DOIs	https://doi.org/10.31339/asm.cp.am-epri-2019p0628
State	Published - 2019
Event	Joint 9th International Conference on Advances in Materials Technology for Fossil Power Plants, EPRI 2019 and the 2nd International 123HiMAT Conference on High-Temperature Materials - Nagasaki, Japan Duration: Oct 21 2019 → Oct 24 2019

Publication series

Name	Joint EPRI-123HiMAT International Conference on Advances in High-Temperature Materials - Proceedings from EPRI's 9th International Conference on Advances in Materials Technology for Fossil Power Plants and the 2nd International 123HiMAT Conference on High-Temperature Materials

Conference

Conference	Joint 9th International Conference on Advances in Materials Technology for Fossil Power Plants, EPRI 2019 and the 2nd International 123HiMAT Conference on High-Temperature Materials
Country/Territory	Japan
City	Nagasaki
Period	10/21/19 → 10/24/19

Funding

The authors thank Drs. Dean Pierce at Oak Ridge National Laboratory, Dr. Kazuhiro Kimura at National Institute for Materials Science, and Dr. Bernd Kuhn at Forschungszentrum Jülich GmbH for the comments on this manuscript and alloy designs in the present study. Research sponsored by the U.S Department of Energy, Office of Fossil Energy, Crosscutting Research Program. A part of this research was conducted at the Center for Nanophase Materials Sciences, which is a DOE Office of Science User Facility. This manuscript has been authored by UT-Battelle, LLC under Contract No. DE-AC05-00OR22725 with the U.S. Department of Energy. The United States Government retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a non-exclusive, paid-up, irrevocable, world-wide license to publish or reproduce the published form of this manuscript, or allow others to do so, for United States Government purposes. The Department of Energy will provide public access to these results of federally sponsored research in accordance with the DOE Public Access Plan (http://energy.gov/downloads/doe-public-access-plan).

Access to Document

10.31339/asm.cp.am-epri-2019p0628

Cite this

Yamamoto, Y., Pint, B. A., Brady, M. P., Babu, S., Kuo, C. H., & Shassere, B. (2019). ALLOY DESIGN AND DEVELOPMENT OF HIGH CR CONTAINING FECRAL FERRITIC ALLOYS FOR EXTREME ENVIRONMENTS. In J. Shingledecker, & M. Takeyama (Eds.), Joint EPRI-123HiMAT International Conference on Advances in High-Temperature Materials - Proceedings from EPRI's 9th International Conference on Advances in Materials Technology for Fossil Power Plants and the 2nd International 123HiMAT Conference on High-Temperature Materials (pp. 628-639). (Joint EPRI-123HiMAT International Conference on Advances in High-Temperature Materials - Proceedings from EPRI's 9th International Conference on Advances in Materials Technology for Fossil Power Plants and the 2nd International 123HiMAT Conference on High-Temperature Materials). ASM International. https://doi.org/10.31339/asm.cp.am-epri-2019p0628

Yamamoto, Yukinori ; Pint, Bruce A. ; Brady, Michael P. et al. / ALLOY DESIGN AND DEVELOPMENT OF HIGH CR CONTAINING FECRAL FERRITIC ALLOYS FOR EXTREME ENVIRONMENTS. Joint EPRI-123HiMAT International Conference on Advances in High-Temperature Materials - Proceedings from EPRI's 9th International Conference on Advances in Materials Technology for Fossil Power Plants and the 2nd International 123HiMAT Conference on High-Temperature Materials. editor / John Shingledecker ; Masao Takeyama. ASM International, 2019. pp. 628-639 (Joint EPRI-123HiMAT International Conference on Advances in High-Temperature Materials - Proceedings from EPRI's 9th International Conference on Advances in Materials Technology for Fossil Power Plants and the 2nd International 123HiMAT Conference on High-Temperature Materials).

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title = "ALLOY DESIGN AND DEVELOPMENT OF HIGH CR CONTAINING FECRAL FERRITIC ALLOYS FOR EXTREME ENVIRONMENTS",

abstract = "A new alloy design concept for creep- and corrosion-resistant, fully ferritic alloys was proposed for high-temperature structural applications in current/future fossil-fired power plants. The alloys, based on the Fe-30Cr-3Al (in weight percent) system with minor alloying additions of Nb, W, Si, Zr and/or Y, were designed for corrosion resistance though high Cr content, steam oxidation resistance through alumina-scale formation, and high-temperature creep performance through fine particle dispersion of Fe2(Nb,W)-type Laves phase in the BCC-Fe matrix. Theses alloys are targeted for use in harsh environments such as combustion and/or steam containing atmospheres at 700°C or greater. The alloys, consisting of Fe-30Cr-3Al-1Nb-6W with minor alloying additions, exhibited a successful combination of oxidation, corrosion, and creep resistances comparable or superior to those of commercially available heat resistant austenitic stainless steels. An optimized thermo-mechanical treatment combined with selected minor alloying additions resulted in a refined grain structure with high thermal stability even at 1200°C, which improved room-temperature ductility without sacrificing the creep performance. The mechanism of grain refinement in the alloy system is discussed.",

author = "Yukinori Yamamoto and Pint, \{Bruce A.\} and Brady, \{Michael P.\} and Sudarsanam Babu and Kuo, \{Chih Hsiang\} and Benjamin Shassere",

note = "Publisher Copyright: {\textcopyright} 2019 ASM International{\textregistered} All rights reserved.; Joint 9th International Conference on Advances in Materials Technology for Fossil Power Plants, EPRI 2019 and the 2nd International 123HiMAT Conference on High-Temperature Materials ; Conference date: 21-10-2019 Through 24-10-2019",

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doi = "10.31339/asm.cp.am-epri-2019p0628",

language = "English",

series = "Joint EPRI-123HiMAT International Conference on Advances in High-Temperature Materials - Proceedings from EPRI's 9th International Conference on Advances in Materials Technology for Fossil Power Plants and the 2nd International 123HiMAT Conference on High-Temperature Materials",

publisher = "ASM International",

pages = "628--639",

editor = "John Shingledecker and Masao Takeyama",

booktitle = "Joint EPRI-123HiMAT International Conference on Advances in High-Temperature Materials - Proceedings from EPRI's 9th International Conference on Advances in Materials Technology for Fossil Power Plants and the 2nd International 123HiMAT Conference on High-Temperature Materials",

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Yamamoto, Y, Pint, BA, Brady, MP, Babu, S, Kuo, CH & Shassere, B 2019, ALLOY DESIGN AND DEVELOPMENT OF HIGH CR CONTAINING FECRAL FERRITIC ALLOYS FOR EXTREME ENVIRONMENTS. in J Shingledecker & M Takeyama (eds), Joint EPRI-123HiMAT International Conference on Advances in High-Temperature Materials - Proceedings from EPRI's 9th International Conference on Advances in Materials Technology for Fossil Power Plants and the 2nd International 123HiMAT Conference on High-Temperature Materials. Joint EPRI-123HiMAT International Conference on Advances in High-Temperature Materials - Proceedings from EPRI's 9th International Conference on Advances in Materials Technology for Fossil Power Plants and the 2nd International 123HiMAT Conference on High-Temperature Materials, ASM International, pp. 628-639, Joint 9th International Conference on Advances in Materials Technology for Fossil Power Plants, EPRI 2019 and the 2nd International 123HiMAT Conference on High-Temperature Materials, Nagasaki, Japan, 10/21/19. https://doi.org/10.31339/asm.cp.am-epri-2019p0628

ALLOY DESIGN AND DEVELOPMENT OF HIGH CR CONTAINING FECRAL FERRITIC ALLOYS FOR EXTREME ENVIRONMENTS. / Yamamoto, Yukinori; Pint, Bruce A.; Brady, Michael P. et al.
Joint EPRI-123HiMAT International Conference on Advances in High-Temperature Materials - Proceedings from EPRI's 9th International Conference on Advances in Materials Technology for Fossil Power Plants and the 2nd International 123HiMAT Conference on High-Temperature Materials. ed. / John Shingledecker; Masao Takeyama. ASM International, 2019. p. 628-639 (Joint EPRI-123HiMAT International Conference on Advances in High-Temperature Materials - Proceedings from EPRI's 9th International Conference on Advances in Materials Technology for Fossil Power Plants and the 2nd International 123HiMAT Conference on High-Temperature Materials).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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T1 - ALLOY DESIGN AND DEVELOPMENT OF HIGH CR CONTAINING FECRAL FERRITIC ALLOYS FOR EXTREME ENVIRONMENTS

AU - Yamamoto, Yukinori

AU - Pint, Bruce A.

AU - Brady, Michael P.

AU - Babu, Sudarsanam

AU - Kuo, Chih Hsiang

AU - Shassere, Benjamin

PY - 2019

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N2 - A new alloy design concept for creep- and corrosion-resistant, fully ferritic alloys was proposed for high-temperature structural applications in current/future fossil-fired power plants. The alloys, based on the Fe-30Cr-3Al (in weight percent) system with minor alloying additions of Nb, W, Si, Zr and/or Y, were designed for corrosion resistance though high Cr content, steam oxidation resistance through alumina-scale formation, and high-temperature creep performance through fine particle dispersion of Fe2(Nb,W)-type Laves phase in the BCC-Fe matrix. Theses alloys are targeted for use in harsh environments such as combustion and/or steam containing atmospheres at 700°C or greater. The alloys, consisting of Fe-30Cr-3Al-1Nb-6W with minor alloying additions, exhibited a successful combination of oxidation, corrosion, and creep resistances comparable or superior to those of commercially available heat resistant austenitic stainless steels. An optimized thermo-mechanical treatment combined with selected minor alloying additions resulted in a refined grain structure with high thermal stability even at 1200°C, which improved room-temperature ductility without sacrificing the creep performance. The mechanism of grain refinement in the alloy system is discussed.

AB - A new alloy design concept for creep- and corrosion-resistant, fully ferritic alloys was proposed for high-temperature structural applications in current/future fossil-fired power plants. The alloys, based on the Fe-30Cr-3Al (in weight percent) system with minor alloying additions of Nb, W, Si, Zr and/or Y, were designed for corrosion resistance though high Cr content, steam oxidation resistance through alumina-scale formation, and high-temperature creep performance through fine particle dispersion of Fe2(Nb,W)-type Laves phase in the BCC-Fe matrix. Theses alloys are targeted for use in harsh environments such as combustion and/or steam containing atmospheres at 700°C or greater. The alloys, consisting of Fe-30Cr-3Al-1Nb-6W with minor alloying additions, exhibited a successful combination of oxidation, corrosion, and creep resistances comparable or superior to those of commercially available heat resistant austenitic stainless steels. An optimized thermo-mechanical treatment combined with selected minor alloying additions resulted in a refined grain structure with high thermal stability even at 1200°C, which improved room-temperature ductility without sacrificing the creep performance. The mechanism of grain refinement in the alloy system is discussed.

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DO - 10.31339/asm.cp.am-epri-2019p0628

M3 - Conference contribution

AN - SCOPUS:85097948886

T3 - Joint EPRI-123HiMAT International Conference on Advances in High-Temperature Materials - Proceedings from EPRI's 9th International Conference on Advances in Materials Technology for Fossil Power Plants and the 2nd International 123HiMAT Conference on High-Temperature Materials

SP - 628

EP - 639

BT - Joint EPRI-123HiMAT International Conference on Advances in High-Temperature Materials - Proceedings from EPRI's 9th International Conference on Advances in Materials Technology for Fossil Power Plants and the 2nd International 123HiMAT Conference on High-Temperature Materials

A2 - Shingledecker, John

A2 - Takeyama, Masao

PB - ASM International

T2 - Joint 9th International Conference on Advances in Materials Technology for Fossil Power Plants, EPRI 2019 and the 2nd International 123HiMAT Conference on High-Temperature Materials

Y2 - 21 October 2019 through 24 October 2019

ER -

Yamamoto Y, Pint BA, Brady MP, Babu S, Kuo CH, Shassere B. ALLOY DESIGN AND DEVELOPMENT OF HIGH CR CONTAINING FECRAL FERRITIC ALLOYS FOR EXTREME ENVIRONMENTS. In Shingledecker J, Takeyama M, editors, Joint EPRI-123HiMAT International Conference on Advances in High-Temperature Materials - Proceedings from EPRI's 9th International Conference on Advances in Materials Technology for Fossil Power Plants and the 2nd International 123HiMAT Conference on High-Temperature Materials. ASM International. 2019. p. 628-639. (Joint EPRI-123HiMAT International Conference on Advances in High-Temperature Materials - Proceedings from EPRI's 9th International Conference on Advances in Materials Technology for Fossil Power Plants and the 2nd International 123HiMAT Conference on High-Temperature Materials). doi: 10.31339/asm.cp.am-epri-2019p0628

ALLOY DESIGN AND DEVELOPMENT OF HIGH CR CONTAINING FECRAL FERRITIC ALLOYS FOR EXTREME ENVIRONMENTS

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