[Ag2M(Te2O5)2]SO4 (M = CeIV or ThIV): A New Purely Inorganic d/f-Heterometallic Cationic Material

Todd N. Poe; Frankie D. White; Vanessa Proust; Eric M. Villa; Matthew J. Polinski

doi:10.1021/acs.inorgchem.8b00504

[Ag₂M(Te₂O₅)2]SO₄ (M = Ce^IV or Th^IV): A New Purely Inorganic d/f-Heterometallic Cationic Material

Todd N. Poe, Frankie D. White, Vanessa Proust, Eric M. Villa, Matthew J. Polinski

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Two new isotypic d/f-heterometallic purely inorganic cationic materials, [Ag₂M(Te₂O₅)₂]SO₄ (M = Ce^IV or Th^IV), were synthesized using the metal oxides (MO₂ and TeO₂), silver nitrate, and sulfuric acid under mild hydrothermal conditions. The prepared materials were characterized via single-crystal X-ray diffraction, which revealed that the materials possess a 3D framework of corner-sharing Te₂O₅^2- units. The tellurite framework creates four unique pores, three of which are occupied by the M^IV and Ag^I metal centers. The tellurite network, metal coordination, and total charge yield a cationic framework, which is charge-balanced by electrostatically bound sulfate anions residing in the largest of the four framework pores. These materials also possess Ag^I in a ligand-imposed linear geometry.

Original language	English
Pages (from-to)	4816-4819
Number of pages	4
Journal	Inorganic Chemistry
Volume	57
Issue number	9
DOIs	https://doi.org/10.1021/acs.inorgchem.8b00504
State	Published - May 7 2018
Externally published	Yes

Funding

T.N.P. and M.J.P. acknowledge Bloomsburg University of Pennsylvania for financial support. E.M.V. acknowledges Creighton University for financial support. F.D.W. acknowledges Florida State University for financial support. V.P. performed optical measurements and was supported, in part, by the Center for Actinide Science and Technology, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences, under Award DESC0016568.

Funders	Funder number
Bloomsburg University of Pennsylvania
Center for Actinide Science and Technology
Florida State University
U.S. Department of Energy
Office of Science
Basic Energy Sciences	DESC0016568
Florida State University
Creighton University

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title = "[Ag2M(Te2O5)2]SO4 (M = CeIV or ThIV): A New Purely Inorganic d/f-Heterometallic Cationic Material",

abstract = "Two new isotypic d/f-heterometallic purely inorganic cationic materials, [Ag2M(Te2O5)2]SO4 (M = CeIV or ThIV), were synthesized using the metal oxides (MO2 and TeO2), silver nitrate, and sulfuric acid under mild hydrothermal conditions. The prepared materials were characterized via single-crystal X-ray diffraction, which revealed that the materials possess a 3D framework of corner-sharing Te2O52- units. The tellurite framework creates four unique pores, three of which are occupied by the MIV and AgI metal centers. The tellurite network, metal coordination, and total charge yield a cationic framework, which is charge-balanced by electrostatically bound sulfate anions residing in the largest of the four framework pores. These materials also possess AgI in a ligand-imposed linear geometry.",

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AU - White, Frankie D.

AU - Proust, Vanessa

AU - Villa, Eric M.

AU - Polinski, Matthew J.

PY - 2018/5/7

Y1 - 2018/5/7

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AB - Two new isotypic d/f-heterometallic purely inorganic cationic materials, [Ag2M(Te2O5)2]SO4 (M = CeIV or ThIV), were synthesized using the metal oxides (MO2 and TeO2), silver nitrate, and sulfuric acid under mild hydrothermal conditions. The prepared materials were characterized via single-crystal X-ray diffraction, which revealed that the materials possess a 3D framework of corner-sharing Te2O52- units. The tellurite framework creates four unique pores, three of which are occupied by the MIV and AgI metal centers. The tellurite network, metal coordination, and total charge yield a cationic framework, which is charge-balanced by electrostatically bound sulfate anions residing in the largest of the four framework pores. These materials also possess AgI in a ligand-imposed linear geometry.

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[Ag₂M(Te₂O₅)2]SO₄ (M = Ce^IV or Th^IV): A New Purely Inorganic d/f-Heterometallic Cationic Material

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