Abstract
Herein, we report a fast (15 min) and solvent-free mechanochemical approach to construct polymers of intrinsic microporosity (PIMs) with high molecular mass and low polydispersity by solid grinding. The enhanced reaction efficiency results from the instantaneous frictional heating and continuous exposure of active sites within those solid reactants.
Original language | English |
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Pages (from-to) | 6739-6741 |
Number of pages | 3 |
Journal | Journal of Materials Chemistry A |
Volume | 3 |
Issue number | 13 |
DOIs | |
State | Published - Apr 7 2015 |