TY - JOUR
T1 - Advanced Materials for Energy-Water Systems
T2 - The Central Role of Water/Solid Interfaces in Adsorption, Reactivity, and Transport
AU - Barry, Edward
AU - Burns, Raelyn
AU - Chen, Wei
AU - De Hoe, Guilhem X.
AU - De Oca, Joan Manuel Montes
AU - De Pablo, Juan J.
AU - Dombrowski, James
AU - Elam, Jeffrey W.
AU - Felts, Alanna M.
AU - Galli, Giulia
AU - Hack, John
AU - He, Qiming
AU - He, Xiang
AU - Hoenig, Eli
AU - Iscen, Aysenur
AU - Kash, Benjamin
AU - Kung, Harold H.
AU - Lewis, Nicholas H.C.
AU - Liu, Chong
AU - Ma, Xinyou
AU - Mane, Anil
AU - Martinson, Alex B.F.
AU - Mulfort, Karen L.
AU - Murphy, Julia
AU - Mølhave, Kristian
AU - Nealey, Paul
AU - Qiao, Yijun
AU - Rozyyev, Vepa
AU - Schatz, George C.
AU - Sibener, Steven J.
AU - Talapin, Dmitri
AU - Tiede, David M.
AU - Tirrell, Matthew V.
AU - Tokmakoff, Andrei
AU - Voth, Gregory A.
AU - Wang, Zhongyang
AU - Ye, Zifan
AU - Yesibolati, Murat
AU - Zaluzec, Nestor J.
AU - Darling, Seth B.
N1 - Publisher Copyright:
©
PY - 2021/8/11
Y1 - 2021/8/11
N2 - The structure, chemistry, and charge of interfaces between materials and aqueous fluids play a central role in determining properties and performance of numerous water systems. Sensors, membranes, sorbents, and heterogeneous catalysts almost uniformly rely on specific interactions between their surfaces and components dissolved or suspended in the water - and often the water molecules themselves - to detect and mitigate contaminants. Deleterious processes in these systems such as fouling, scaling (inorganic deposits), and corrosion are also governed by interfacial phenomena. Despite the importance of these interfaces, much remains to be learned about their multiscale interactions. Developing a deeper understanding of the molecular- and mesoscale phenomena at water/solid interfaces will be essential to driving innovation to address grand challenges in supplying sufficient fit-for-purpose water in the future. In this Review, we examine the current state of knowledge surrounding adsorption, reactivity, and transport in several key classes of water/solid interfaces, drawing on a synergistic combination of theory, simulation, and experiments, and provide an outlook for prioritizing strategic research directions.
AB - The structure, chemistry, and charge of interfaces between materials and aqueous fluids play a central role in determining properties and performance of numerous water systems. Sensors, membranes, sorbents, and heterogeneous catalysts almost uniformly rely on specific interactions between their surfaces and components dissolved or suspended in the water - and often the water molecules themselves - to detect and mitigate contaminants. Deleterious processes in these systems such as fouling, scaling (inorganic deposits), and corrosion are also governed by interfacial phenomena. Despite the importance of these interfaces, much remains to be learned about their multiscale interactions. Developing a deeper understanding of the molecular- and mesoscale phenomena at water/solid interfaces will be essential to driving innovation to address grand challenges in supplying sufficient fit-for-purpose water in the future. In this Review, we examine the current state of knowledge surrounding adsorption, reactivity, and transport in several key classes of water/solid interfaces, drawing on a synergistic combination of theory, simulation, and experiments, and provide an outlook for prioritizing strategic research directions.
UR - http://www.scopus.com/inward/record.url?scp=85110958352&partnerID=8YFLogxK
U2 - 10.1021/acs.chemrev.1c00069
DO - 10.1021/acs.chemrev.1c00069
M3 - Review article
C2 - 34213328
AN - SCOPUS:85110958352
SN - 0009-2665
VL - 121
SP - 9450
EP - 9501
JO - Chemical Reviews
JF - Chemical Reviews
IS - 15
ER -