Addition of CFCl3 to aromatic aldehydes via in situ Grignard reaction

Balaka Barkakaty; Bandana Talukdar; Bradley S. Lokitz

doi:10.3390/molecules200815098

Addition of CFCl₃ to aromatic aldehydes via in situ Grignard reaction

Balaka Barkakaty
, Bandana Talukdar
, Bradley S. Lokitz

Center for Nanophase Matls Sciences

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Synthetic modification of trichlorofluoromethane (CFCl₃) to non-volatile and useful fluorinated precursors is a cost-effective and an environmentally benign strategy for the safe consumption/destruction of the ozone depleting potential of the reagent. In this report, we present a novel method for in situ Grignard reaction using magnesium powder and CFCl₃ for synthesis of dichlorofluoromethyl aromatic alcohols.

Original language	English
Pages (from-to)	15098-15107
Number of pages	10
Journal	Molecules
Volume	20
Issue number	8
DOIs	https://doi.org/10.3390/molecules200815098
State	Published - Aug 1 2015

Keywords

Aromatic aldehydes
CFCl
Grignard reaction
In-situ process
Magnesium

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10.3390/molecules200815098

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title = "Addition of CFCl3 to aromatic aldehydes via in situ Grignard reaction",

abstract = "Synthetic modification of trichlorofluoromethane (CFCl3) to non-volatile and useful fluorinated precursors is a cost-effective and an environmentally benign strategy for the safe consumption/destruction of the ozone depleting potential of the reagent. In this report, we present a novel method for in situ Grignard reaction using magnesium powder and CFCl3 for synthesis of dichlorofluoromethyl aromatic alcohols.",

keywords = "Aromatic aldehydes, CFCl, Grignard reaction, In-situ process, Magnesium",

author = "Balaka Barkakaty and Bandana Talukdar and Lokitz, \{Bradley S.\}",

note = "Publisher Copyright: {\textcopyright} 2015 by the authors.",

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AU - Barkakaty, Balaka

AU - Talukdar, Bandana

AU - Lokitz, Bradley S.

PY - 2015/8/1

Y1 - 2015/8/1

N2 - Synthetic modification of trichlorofluoromethane (CFCl3) to non-volatile and useful fluorinated precursors is a cost-effective and an environmentally benign strategy for the safe consumption/destruction of the ozone depleting potential of the reagent. In this report, we present a novel method for in situ Grignard reaction using magnesium powder and CFCl3 for synthesis of dichlorofluoromethyl aromatic alcohols.

AB - Synthetic modification of trichlorofluoromethane (CFCl3) to non-volatile and useful fluorinated precursors is a cost-effective and an environmentally benign strategy for the safe consumption/destruction of the ozone depleting potential of the reagent. In this report, we present a novel method for in situ Grignard reaction using magnesium powder and CFCl3 for synthesis of dichlorofluoromethyl aromatic alcohols.

KW - Aromatic aldehydes

KW - CFCl

KW - Grignard reaction

KW - In-situ process

KW - Magnesium

UR - https://www.scopus.com/pages/publications/84941254915

U2 - 10.3390/molecules200815098

DO - 10.3390/molecules200815098

M3 - Article

C2 - 26295221

AN - SCOPUS:84941254915

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VL - 20

SP - 15098

EP - 15107

JO - Molecules

JF - Molecules

IS - 8

ER -

Addition of CFCl₃ to aromatic aldehydes via in situ Grignard reaction

Abstract

Keywords

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