Addition of CFCl3 to aromatic aldehydes via in situ Grignard reaction

Balaka Barkakaty; Bandana Talukdar; Bradley S. Lokitz

doi:10.3390/molecules200815098

Addition of CFCl₃ to aromatic aldehydes via in situ Grignard reaction

Balaka Barkakaty, Bandana Talukdar, Bradley S. Lokitz

Center for Nanophase Matls Sciences

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Synthetic modification of trichlorofluoromethane (CFCl₃) to non-volatile and useful fluorinated precursors is a cost-effective and an environmentally benign strategy for the safe consumption/destruction of the ozone depleting potential of the reagent. In this report, we present a novel method for in situ Grignard reaction using magnesium powder and CFCl₃ for synthesis of dichlorofluoromethyl aromatic alcohols.

Original language	English
Pages (from-to)	15098-15107
Number of pages	10
Journal	Molecules
Volume	20
Issue number	8
DOIs	https://doi.org/10.3390/molecules200815098
State	Published - Aug 1 2015

Keywords

Aromatic aldehydes
CFCl
Grignard reaction
In-situ process
Magnesium

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10.3390/molecules200815098

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abstract = "Synthetic modification of trichlorofluoromethane (CFCl3) to non-volatile and useful fluorinated precursors is a cost-effective and an environmentally benign strategy for the safe consumption/destruction of the ozone depleting potential of the reagent. In this report, we present a novel method for in situ Grignard reaction using magnesium powder and CFCl3 for synthesis of dichlorofluoromethyl aromatic alcohols.",

keywords = "Aromatic aldehydes, CFCl, Grignard reaction, In-situ process, Magnesium",

author = "Balaka Barkakaty and Bandana Talukdar and Lokitz, {Bradley S.}",

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AB - Synthetic modification of trichlorofluoromethane (CFCl3) to non-volatile and useful fluorinated precursors is a cost-effective and an environmentally benign strategy for the safe consumption/destruction of the ozone depleting potential of the reagent. In this report, we present a novel method for in situ Grignard reaction using magnesium powder and CFCl3 for synthesis of dichlorofluoromethyl aromatic alcohols.

KW - Aromatic aldehydes

KW - CFCl

KW - Grignard reaction

KW - In-situ process

KW - Magnesium

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Addition of CFCl₃ to aromatic aldehydes via in situ Grignard reaction

Abstract

Keywords

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