Abstract
Absolute total cross sections for electron-impact excitation of the Be-like C2+, N3+, and O4+ ions have been measured near threshold using the merged electron-ion beams energy-loss (MEIBEL) technique and calculated using a close-coupling R-matrix (CCR) approach. The 2s2 1S → 2s2p 1P0 dipole-allowed transition from the ground state was investigated for all three ions and satisfactory agreement between experiment and theory is found. In addition, calculations and measurements for the 2s2p 3P0 → 2p2 3P allowed transition from the metastable level of C2+ are in excellent agreement. The sum of the cross sections for the 2s2 1S → 2s2p 3P0 and 2s2p 3P0 → 2s2p 1P0 spin-forbidden transitions, not completely resolved by the MEIBEL technique, are measured for C2+ and O4+ and compared to CCR calculations scaled to account for the ground state and metastable fractions of the target ion beams. The results for these unresolved transitions are in reasonable agreement except for a resonance feature measured in the 2s2p 3P0 → 2s2p 1P0 transition in C2+ that is not predicted by theory.
| Original language | English |
|---|---|
| Pages (from-to) | 39-48 |
| Number of pages | 10 |
| Journal | International Journal of Mass Spectrometry |
| Volume | 192 |
| Issue number | 1-3 |
| DOIs | |
| State | Published - 1999 |
Funding
This research was supported by the Office of Fusion Energy Sciences of the U.S. Department of Energy under contract no. DE-AC05-96OR22464 with Lockheed Martin Energy Research Corp. and contract no. DE-A102-95ER54293 with the National Institute of Standards and Technology.
Keywords
- Close coupling
- Collisions
- Excitation
- Merged beams